Can emerging membrane-based desalination technologies replace reverse osmosis?

Abstract: Growing uncertainty in the future availability of freshwater sources has led to an increase in installations for desalination of seawater. Reverse osmosis (RO), currently the most widely adopted desalination technique, has caused environmental concerns over the high associated greenhouse gas emissions and generation of large amounts of chemicals-containing brine. Significant consumption of electricity for RO desalination is an additional challenge, particularly in remote locations. In this review, forward osmosis (FO), membrane distillation (MD) and capacitive deionization (CDI) are assessed as potential substitute technologies and the major recent advancements in each field are discussed. These emerging technologies offer significant advantages over RO, such as higher salt rejection (CDI, MD), higher recovery of water (MD), fewer pre-treatment stages (MD, FO) and the ability to use low-grade energy (MD, FO). In their current state, stand-alone technologies cannot compete with RO until certain challenges are addressed, including pore-wetting (MD) and high energy consumption (MD, CDI, FO). Hybrid systems that combine RO and emerging technologies may be useful for feed waters that cannot be treated by RO alone and their benefits may be able to offset the increase in capital costs. These and other aspects, such as operational stability of hybrid systems, should be considered further in large-scale, long-term studies
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Can emerging membrane-based desalination technologies replace reverse osmosis?

Abstract: Growing uncertainty in the future availability of freshwater sources has led to an increase in installations for desalination of seawater. Reverse osmosis (RO), currently the most widely adopted desalination technique, has caused environmental concerns over the high associated greenhouse gas emissions and generation of large amounts of chemicals-containing brine. Significant consumption of electricity for RO desalination is an additional challenge, particularly in remote locations. In this review, forward osmosis (FO), membrane distillation (MD) and capacitive deionization (CDI) are assessed as potential substitute technologies and the major recent advancements in each field are discussed. These emerging technologies offer significant advantages over RO, such as higher salt rejection (CDI, MD), higher recovery of water (MD), fewer pre-treatment stages (MD, FO) and the ability to use low-grade energy (MD, FO). In their current state, stand-alone technologies cannot compete with RO until certain challenges are addressed, including pore-wetting (MD) and high energy consumption (MD, CDI, FO). Hybrid systems that combine RO and emerging technologies may be useful for feed waters that cannot be treated by RO alone and their benefits may be able to offset the increase in capital costs. These and other aspects, such as operational stability of hybrid systems, should be considered further in large-scale, long-term studies

Development of Photovoltaic Electrodialysis Desalination System

ABSTRACT: The declining supply of drinking water for an increasing world population is a global concern with impacts on public health as well as micro and macro economies. A Photovoltaic Electrodialysis (PV-ED) unit is designed and constructed. The unit consists of a direct current power supply that charges batteries to provide a constant current to the unit. This includes an electrodialysis stack (desalinization unit), circulation pumps, a concentrate discharge unit, and a control unit to communicate between the photovoltaic and electrodialysis systems. The controller unit in conjunction with several sensors to monitor flow, conductivity, pressure, water elevation levels, and temperature creates a closed loop feedback system. The logic used in the control system was developed after physical construction of the unit. A closed loop feedback system allows battery charging, power regulation, and product water parameters to be precisely controlled while maintaining maximum efficiency. Based on the experience obtained during this research, the team at Cal Poly Pomona has estimated that this small PV-ED unit can be manufacture with a unit cost of $4,000. The Cal Poly Pomona team is looking into opportunities for implementation of this decentralized PV-ED unit in a disadvantaged community (DAC) in California.
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Development of Photovoltaic Electrodialysis Desalination System

ABSTRACT: The declining supply of drinking water for an increasing world population is a global concern with impacts on public health as well as micro and macro economies. A Photovoltaic Electrodialysis (PV-ED) unit is designed and constructed. The unit consists of a direct current power supply that charges batteries to provide a constant current to the unit. This includes an electrodialysis stack (desalinization unit), circulation pumps, a concentrate discharge unit, and a control unit to communicate between the photovoltaic and electrodialysis systems. The controller unit in conjunction with several sensors to monitor flow, conductivity, pressure, water elevation levels, and temperature creates a closed loop feedback system. The logic used in the control system was developed after physical construction of the unit. A closed loop feedback system allows battery charging, power regulation, and product water parameters to be precisely controlled while maintaining maximum efficiency. Based on the experience obtained during this research, the team at Cal Poly Pomona has estimated that this small PV-ED unit can be manufacture with a unit cost of $4,000. The Cal Poly Pomona team is looking into opportunities for implementation of this decentralized PV-ED unit in a disadvantaged community (DAC) in California.

Development, Modeling, Analysis, and Optimization of a Novel Inland Desalination with Zero Liquid Discharge for Brackish Groundwaters

ABSTRACT: Groundwater is considered the major source of domestic water supply in many countries worldwide. In the absence of surface water supplies, the use of groundwater for domestic, agricultural, and even for industrial purposes becomes essential, especially in rural communities. Groundwater supplies typically are of good quality, and the quality is reasonably uniform throughout the year compared to that of surface water, thus making it suitable for direct use, or simple to treat. A disadvantage of groundwater is the content of dissolved salt as many have a moderate-to-high salinity. The high salinity makes water brackish and thus it requires desalination before use. This has led to wide use of groundwater desalination to produce good-quality water in many regions around the world. Nevertheless, a problem of desalination processes is the generation of a concentrate stream, sometimes called brine or reject, which must be properly managed. The management of brine from brackish groundwater desalination is a significant issue if located far from the coast (i.e. inland plants) or far from public channel to discharge such brine. Some options for brine disposal from inland desalination plants are evaporation ponds, deepwell injection, disposal to municipal sewers, and irrigation of plants tolerant to high salinities. Each of these disposal methods may result in many environmental problems such as groundwater contamination, the decline in crop yields from agricultural lands, the formation of eyesores, decreasing the efficiency of biological wastewater treatment, and making treated sewage effluent unsuitable for irrigation. As a result, the brine management from inland desalination of brackish groundwater is very critical, and the need for affordable and environmentally benign inland desalination has become crucial in many regions worldwide. This work aims to develop an efficient and environmentally benign process for inland desalination of brackish groundwater, which approaches zero liquid discharge (ZLD), maximizing the water produced and minimizing the volume of concentrate effluent. The technical approach involves utilization of two-stage reverse osmosis (RO) units with the intermediate chemical treatment of brine stream that is designed to remove most of the scale-forming constituents, which foul membrane surface in RO and limits its water recovery and hence enable further recovery of water in the secondary RO unit.
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Development, Modeling, Analysis, and Optimization of a Novel Inland Desalination with Zero Liquid Discharge for Brackish Groundwaters

ABSTRACT: Groundwater is considered the major source of domestic water supply in many countries worldwide. In the absence of surface water supplies, the use of groundwater for domestic, agricultural, and even for industrial purposes becomes essential, especially in rural communities. Groundwater supplies typically are of good quality, and the quality is reasonably uniform throughout the year compared to that of surface water, thus making it suitable for direct use, or simple to treat. A disadvantage of groundwater is the content of dissolved salt as many have a moderate-to-high salinity. The high salinity makes water brackish and thus it requires desalination before use. This has led to wide use of groundwater desalination to produce good-quality water in many regions around the world. Nevertheless, a problem of desalination processes is the generation of a concentrate stream, sometimes called brine or reject, which must be properly managed. The management of brine from brackish groundwater desalination is a significant issue if located far from the coast (i.e. inland plants) or far from public channel to discharge such brine. Some options for brine disposal from inland desalination plants are evaporation ponds, deepwell injection, disposal to municipal sewers, and irrigation of plants tolerant to high salinities. Each of these disposal methods may result in many environmental problems such as groundwater contamination, the decline in crop yields from agricultural lands, the formation of eyesores, decreasing the efficiency of biological wastewater treatment, and making treated sewage effluent unsuitable for irrigation. As a result, the brine management from inland desalination of brackish groundwater is very critical, and the need for affordable and environmentally benign inland desalination has become crucial in many regions worldwide. This work aims to develop an efficient and environmentally benign process for inland desalination of brackish groundwater, which approaches zero liquid discharge (ZLD), maximizing the water produced and minimizing the volume of concentrate effluent. The technical approach involves utilization of two-stage reverse osmosis (RO) units with the intermediate chemical treatment of brine stream that is designed to remove most of the scale-forming constituents, which foul membrane surface in RO and limits its water recovery and hence enable further recovery of water in the secondary RO unit.

Designing of Reverse Osmosis Desalination Plant in Jordan Valley Using Optimal Energy Options With Less Environmental Impacts

General introduction: When population growing, water demand for domestic, agricultural and industrial needs is increasing. Fresh water resources are now widely exploited over the world due to increasing population and the amount of potable water will be decreased so, the other sources of water require some form of treatment before potable use without interruption and with reasonable cost to the consumer. Desalination technologies have appeared since 1950s at large scale plant with thermal processes like Multi Stage Flash Distillation (MSF) and Multi Effect Distillation (MED). Heating processes became established using the plenty supply of available oil-driven energy for the required heating process[1]. The Reverse Osmosis (RO) process, developed since 1970s, is the main alternative to the previous technologies that require less amount of energy than thermal processes [1]. The desalination of ground water has more interest especially in Jordan Valley region due to high amount of salinity (Total Dissolve solids TDS). The design and operation of treatment plant depends on the feed water quality in order to decide which pretreatment, feed pressure, recovery and waste disposable method is selected since the energy consumption is related directly to feed water TDS[2]
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Designing of Reverse Osmosis Desalination Plant in Jordan Valley Using Optimal Energy Options With Less Environmental Impacts

General introduction: When population growing, water demand for domestic, agricultural and industrial needs is increasing. Fresh water resources are now widely exploited over the world due to increasing population and the amount of potable water will be decreased so, the other sources of water require some form of treatment before potable use without interruption and with reasonable cost to the consumer. Desalination technologies have appeared since 1950s at large scale plant with thermal processes like Multi Stage Flash Distillation (MSF) and Multi Effect Distillation (MED). Heating processes became established using the plenty supply of available oil-driven energy for the required heating process[1]. The Reverse Osmosis (RO) process, developed since 1970s, is the main alternative to the previous technologies that require less amount of energy than thermal processes [1]. The desalination of ground water has more interest especially in Jordan Valley region due to high amount of salinity (Total Dissolve solids TDS). The design and operation of treatment plant depends on the feed water quality in order to decide which pretreatment, feed pressure, recovery and waste disposable method is selected since the energy consumption is related directly to feed water TDS[2]

Designing And Optimizing 10,000 m 3 /day Conventional SWRO Desalination plant

ABSTRACT: Desalination of seawater has been considered as one of the most promising techniques for supplying a fresh water in Libya. Reverse osmosis (RO) is one of the main technologies for big size desalination plants for the reason that it offers an ability of producing a high quality and quantity of fresh water from seawater with a minor specific energy consumption compared to the other thermal evaporation processes. This paper aims to collect and apply the most useful mathematical equations and software of designing a seawater RO desalination plant with a capacity of 10,000 m3/day. Moreover, its pretreatment equipment such as sedimentation tank, high-pressure pump, multimedia and cartridge filters. IMSdesign software developed by Nitto Hydranuatics Company used for designing and optimizing the membrane assembly of the suggested plant. Additionally, the energy recovery device (ERD) specification accomplished by the same earlier software. In addition, the recommended antiscalant dose predicted by PWT ProDose software. The recovery of the plant increased to more than 40% with less number of membrane elements due to installing new advanced membranes (SWC6 MAX) developed by Nitto Hydranuatics Company. Moreover, pressure exchanger device recommended for the designed plant to decrease the specific pumping energy from 4.81 kWh/m3 to 2.09 kWh/m3, which saves more energy, thus, decreases the unit product cost of the plant.
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Designing And Optimizing 10,000 m 3 /day Conventional SWRO Desalination plant

ABSTRACT: Desalination of seawater has been considered as one of the most promising techniques for supplying a fresh water in Libya. Reverse osmosis (RO) is one of the main technologies for big size desalination plants for the reason that it offers an ability of producing a high quality and quantity of fresh water from seawater with a minor specific energy consumption compared to the other thermal evaporation processes. This paper aims to collect and apply the most useful mathematical equations and software of designing a seawater RO desalination plant with a capacity of 10,000 m3/day. Moreover, its pretreatment equipment such as sedimentation tank, high-pressure pump, multimedia and cartridge filters. IMSdesign software developed by Nitto Hydranuatics Company used for designing and optimizing the membrane assembly of the suggested plant. Additionally, the energy recovery device (ERD) specification accomplished by the same earlier software. In addition, the recommended antiscalant dose predicted by PWT ProDose software. The recovery of the plant increased to more than 40% with less number of membrane elements due to installing new advanced membranes (SWC6 MAX) developed by Nitto Hydranuatics Company. Moreover, pressure exchanger device recommended for the designed plant to decrease the specific pumping energy from 4.81 kWh/m3 to 2.09 kWh/m3, which saves more energy, thus, decreases the unit product cost of the plant.

Design Of A Desalination Plant Aspects To Consider

Abstract: One of the main problems our actual society faces is the shortage of water. Despite the great effort made by authorities and researchers, multiple countries with poor economic resources are experiencing serious difficulties derivative of water scarcity. Desalination provides a feasible solution for inland and coastal areas. Through literature and reviewed articles analysis the reader will meet the actual issues regarding designing a desalination plant, and more over with reverse osmosis (RO) processes, which are the main arguments of this work. One of the big deals is the environmental concern when handling the concentrate disposal. Another important point about desalination processes is the increasingly interest in coupling the units with renewable energy sources (RES). The results point out that regardless of the efforts made until today, additional achievement is required in fields such as membrane’s structure materials for RO method, concentrate disposal systems, governmental water policies review and update, and greater distinction researches between brackish water and seawater RO desalination processes. Taking into consideration the previous outcomes it is finally concluded that some particular steps must be accomplished when beginning a desalination plant design
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Design Of A Desalination Plant Aspects To Consider

Abstract: One of the main problems our actual society faces is the shortage of water. Despite the great effort made by authorities and researchers, multiple countries with poor economic resources are experiencing serious difficulties derivative of water scarcity. Desalination provides a feasible solution for inland and coastal areas. Through literature and reviewed articles analysis the reader will meet the actual issues regarding designing a desalination plant, and more over with reverse osmosis (RO) processes, which are the main arguments of this work. One of the big deals is the environmental concern when handling the concentrate disposal. Another important point about desalination processes is the increasingly interest in coupling the units with renewable energy sources (RES). The results point out that regardless of the efforts made until today, additional achievement is required in fields such as membrane’s structure materials for RO method, concentrate disposal systems, governmental water policies review and update, and greater distinction researches between brackish water and seawater RO desalination processes. Taking into consideration the previous outcomes it is finally concluded that some particular steps must be accomplished when beginning a desalination plant design
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