Chlorine Dioxide Effectiveness on Microbial Corrosion Case Study

The goal of this project is to validate proof-of-concept testing for iron enriched granular activated carbon (GAC) composites (aerogel-GAC or iron-oxide impregnated) as a viable adsorbent for removing arsenic from groundwater and conduct technical and economic feasibility assessments for these innovative processes. Specific project objectives include: • Conduct batch experiments for aerogel-GAC and Fe-oxide impregnated GAC composites to evaluate their performance removing arsenic. • Evaluate Fe-GAC media performance in rapid small scale column tests (RSSCTs) to assess arsenic removal in a more dynamic treatment system. • Evaluate Fe-GAC potential for removal of other contaminants (e.g., methyl tertiary butyl ether, dissolved organic carbon). • Characterize Fe-GAC media. • Correlate performance and media characterization for possible selection of two media for a future second phase of this project.

The 2006 version of the Pa. DEP Inorganic Contaminant Removal module has detailed advanced treatment information on this topic and can be obtained by e-mailing the Pa. DEP Safe Drinking Water Training Section at DEPWSTechtrain@pa.gov to request a copy. This advanced module has additional information on the removal of various inorganic contaminants as well as on oxidation, ion exchange, activated alumina and sequestration. The 2006 document also includes more detailed information on the inorganic contaminant treatments of GAC (granular activated carbon), coagulation/filtration, membranes, and lime softening. It includes the following information:

• Inorganic contaminant treatment selection considerations
• Advanced inorganic contaminant removal chemistry terminology
• Advanced inorganic contaminant removal chemistry explanations
• Conventional filtration and how it relates to inorganic removal
• Detailed information on treatments for iron and manganese removal
• Detailed information on treatments for hardness removal
• Detailed information on inorganic contaminant monitoring protocols
• Detailed tables on the following topics:
• Sources of 26 inorganic contaminants
• Common secondary standards with effects, inorganic contributors and indications
• Various treatment technology options to consider for 24 inorganic contaminants
• Potential forms of iron and manganese
• Iron and manganese sampling procedures
• Iron and manganese oxidant selection criteria
• Iron and manganese theoretical (initial) dosing criteria
• Potential treatments for less common inorganics
• Potential treatments for miscellaneous trace metals

Introduction: Desalination using seawater reverse osmosis (SWRO) technology is an important option available to water-scarce coastal regions. Worldwide sea water desalination is a very effective and economical way of producing potable water for drinking and industries. Reverse osmosis plants to convert sea water to potable drinking water and for other usages have been prevalent throughout the world for more than 4 decades. Design and operation of seawater reverse osmosis plants strongly depend on the raw seawater quality to be treated. The performance of desalination reverse osmosis (RO) systems relies upon the production of high quality pre treated water, and the selection of the best pre treatment technology depends on the raw seawater quality and its variations. Number of full-scale experiences has shown that pre treatment is the key for this application of reverse osmosis technology. It is why during these last years, an import effort has been done to identify and to characterise the diverse organic and mineral components present in the seawater in a view to optimise the seawater pre-treatment and to develop advanced analytical methods for feed water characterization, appropriate fouling indicators and prediction tools. This Chapter describes firstly a comprehensive approach to characterize raw seawater samples through analytical tools which allow the knowledge of the characterization of seawater from many aspects: (a) inorganic content, (b) natural organic matter, (c) enumeration of micro-organisms and phytoplankton. Secondly, this Chapter describes the effect of each of these parameters on the fouling of the reverse osmosis membrane. Finally, this chapter describes the different possible pre treatments available to reduce or remove the elements or substances up-stream reverse osmosis stage.

New regulations pursuant to The Drinking Water Safety Act, administered by the Office of Drinking Water, resulted in changes to the approval, licensing, monitoring, record-keeping and reporting requirements for drinking water systems in Manitoba. It is recognized that many small drinking water systems may not have the same level of access to technical services and resources as larger public water systems. This manual of best practices (a comprehensive, integrated and co-operative approach to continuous improvement of all facets of operations for delivering superior standards of performance) is to assist small drinking water systems with regulatory, management and operational challenges.

Surging population, energy demands, and climate change will push us, ever more urgently, to find new approaches to meet growing water demands. Most often, this will involve harvesting lower quality or impaired water supplies (e.g., seawater or brackish groundwater) as a source for drinking water. Recently desalination using membrane-based processes (e.g., reverse osmosis [RO], electrodialysis [ED], and nanofiltration [NF]) has shown promise for providing additional sources of fresh water across the United States. However, the current membrane separation processes are commonly energy intensive and produce large volumes of concentrated brine which poses unique challenges. Particularly in land-locked urban center brine disposal often relyes on surface water discharge or deep-well injection which pose economic and practical difficulties for wide-spread adoption of such technologies. Thus, there is an urgent need for energy-efficient desalination technologies that reduce the amount of concentrate produced, or identify cost-effective solutions for concentrate management.