Desalination By Electret Technology
Desalination by electret technology
Source : https://www.elsevier.com/en-xm
Author(s) : Haifeng Ni, Robert C. Amine , Yah Jin
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A purification process of making use of electret technology for efficient but cost effective deionization was discussed in this paper. Douglas MacGregor claimed that PTFE electret works as a means of ions separation for desalination due to the polarization of an electrolyte and ions migration under a permanent electrostatic field generated by a pair of electrets with opposite polarities.
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Determination of Optimal Operating Condition in Nanofiltration (NF) and Reverse Osmosis (RO) During The Treatment of a Tannery Wastewater Stream
Introduction
Industrial wastewater treatment, such as those used for tannery wastewater, is complex due to the variety of chemicals added at different stages of processing of hides and skins. Major problems in tanneries are due to wastewater containing heavy metals, toxic chemicals, chloride, lime with high dissolved and suspended salts and other pollutants (Uberoi, 2003). The tanning process and the effluents generated have already been reported in literature (Wiegant et al., 1999, Sreeram and Ramasami, 2003, Stoop, 2003). Many conventional processes were carried out to treat wastewater such as biological process (Ahn et al., 1996, Vijayaraghavan and Murthy, 1997, Wiemann et al., 1998, Di Iaconi et al., 2003, Farabegoli et al., 2004), oxidation process (Sekaran et al., 1996, Dogruel et al., 2004, Sacco et al., 2012, de Caprariis et al., 2012) and chemical process (Di Iaconi et al., 2001, Orhon et al., 1998, Song et al., 2004) etc. Among these, physical and chemical methods are considered very expensive in terms of energy and reagents consumption (Churchley, 1994, Stern et al., 2003), and generation of excessive sludge (Chu, 2001). To reduce the production of sludge by the treatment of this wastewater combined or alternative systems must be explored. In particular, in this work, two spiral wound membrane modules were used: nanofiltration (NF) and reverse osmosis (RO). The goal of this approach is to insert membranes into the cycle of wastewater treatment in order to remove the entire chain of biological treatment and the resulting post physico[1]chemical residue with a significant reduction of sludge up to 95%. A modified version of the traditional method used to measure critical fluxes of membranes, that is the pressure cycling method, was applied to measure both the critical and the threshold flux on the nanofiltration membrane in order to optimize the operating conditions. Once obtained the critical and threshold flux values, this data was used as input for a batch membrane process optimization method developed previously by Stoller at al. (Stoller and Chianese, 2006, Stoller and Bravi, 2010, Stoller, 2009, Iaquinta et al., 2009, Stoller, 2008, Stoller, 2011). The output of the method indicates the optimal permeate feed flow rate which should be used during the batch in order to inhibit membrane fouling. Finally, the obtained results were compared from an economical point of view with a conventional biological process to validate the membrane plant as possible alternative to conventional process.
Determination of Optimal Operating Condition in Nanofiltration (NF) and Reverse Osmosis (RO) During The Treatment of a Tannery Wastewater Stream
Introduction
Industrial wastewater treatment, such as those used for tannery wastewater, is complex due to the variety of chemicals added at different stages of processing of hides and skins. Major problems in tanneries are due to wastewater containing heavy metals, toxic chemicals, chloride, lime with high dissolved and suspended salts and other pollutants (Uberoi, 2003). The tanning process and the effluents generated have already been reported in literature (Wiegant et al., 1999, Sreeram and Ramasami, 2003, Stoop, 2003). Many conventional processes were carried out to treat wastewater such as biological process (Ahn et al., 1996, Vijayaraghavan and Murthy, 1997, Wiemann et al., 1998, Di Iaconi et al., 2003, Farabegoli et al., 2004), oxidation process (Sekaran et al., 1996, Dogruel et al., 2004, Sacco et al., 2012, de Caprariis et al., 2012) and chemical process (Di Iaconi et al., 2001, Orhon et al., 1998, Song et al., 2004) etc. Among these, physical and chemical methods are considered very expensive in terms of energy and reagents consumption (Churchley, 1994, Stern et al., 2003), and generation of excessive sludge (Chu, 2001). To reduce the production of sludge by the treatment of this wastewater combined or alternative systems must be explored. In particular, in this work, two spiral wound membrane modules were used: nanofiltration (NF) and reverse osmosis (RO). The goal of this approach is to insert membranes into the cycle of wastewater treatment in order to remove the entire chain of biological treatment and the resulting post physico[1]chemical residue with a significant reduction of sludge up to 95%. A modified version of the traditional method used to measure critical fluxes of membranes, that is the pressure cycling method, was applied to measure both the critical and the threshold flux on the nanofiltration membrane in order to optimize the operating conditions. Once obtained the critical and threshold flux values, this data was used as input for a batch membrane process optimization method developed previously by Stoller at al. (Stoller and Chianese, 2006, Stoller and Bravi, 2010, Stoller, 2009, Iaquinta et al., 2009, Stoller, 2008, Stoller, 2011). The output of the method indicates the optimal permeate feed flow rate which should be used during the batch in order to inhibit membrane fouling. Finally, the obtained results were compared from an economical point of view with a conventional biological process to validate the membrane plant as possible alternative to conventional process.
A Review of Reverse Osmosis Membrane Fouling and Control Strategies
Introduction
This paper reviews membrane contamination and dirt Control strategies, focusing on the latest developments.
The first goal From this paper is to illustrate the types of dirt.
The second goal is To discuss the latest pollution mitigation strategies, including pre-treatment, monitoring, cleaning, and surface modification as well as updates.
A Review of Reverse Osmosis Membrane Fouling and Control Strategies
Introduction
This paper reviews membrane contamination and dirt Control strategies, focusing on the latest developments.
The first goal From this paper is to illustrate the types of dirt.
The second goal is To discuss the latest pollution mitigation strategies, including pre-treatment, monitoring, cleaning, and surface modification as well as updates.
A Pilot Study of an Electromagnetic Field for Control of Reverse Osmosis Membrane Fouling and Scaling During Brackish Groundwater Desalination
Abstract: This study investigated the effects of an electromagnetic field (EMF) on control of membrane
fouling and scaling during desalination of brackish groundwater using a pilot reverse osmosis (RO)
skid. The groundwater was primarily CaSO4 type with a total dissolved solids concentration of
5850 mg/L and hardness of 2500 mg/L as CaCO3. Two EMF devices were installed in the pipeline
before a cartridge filter and in the RO feed inlet to induce an electric signal of ±150 kHz to the
groundwater. The effects of EMF on membrane scaling were evaluated under accelerated conditions,
i.e., without pH adjustment and addition of antiscalant. Two-phase experiments were conducted:
Phase 1 (376 h) with the EMF devices turned on after 150 h baseline operation; and Phase 2 (753 h)
with the EMF devices turned on from the beginning of testing. The EMF significantly reduced
membrane scaling and improved RO performance by 38.3% and 14.3% in terms of normalized water
permeability decline rate after 150 h and 370 h operation, respectively. Membrane autopsy results
indicated that the fouling layer formed under the influence of EMF was loose with a low density and
was easily removed by hydraulic flushing
A Pilot Study of an Electromagnetic Field for Control of Reverse Osmosis Membrane Fouling and Scaling During Brackish Groundwater Desalination
Abstract: This study investigated the effects of an electromagnetic field (EMF) on control of membrane
fouling and scaling during desalination of brackish groundwater using a pilot reverse osmosis (RO)
skid. The groundwater was primarily CaSO4 type with a total dissolved solids concentration of
5850 mg/L and hardness of 2500 mg/L as CaCO3. Two EMF devices were installed in the pipeline
before a cartridge filter and in the RO feed inlet to induce an electric signal of ±150 kHz to the
groundwater. The effects of EMF on membrane scaling were evaluated under accelerated conditions,
i.e., without pH adjustment and addition of antiscalant. Two-phase experiments were conducted:
Phase 1 (376 h) with the EMF devices turned on after 150 h baseline operation; and Phase 2 (753 h)
with the EMF devices turned on from the beginning of testing. The EMF significantly reduced
membrane scaling and improved RO performance by 38.3% and 14.3% in terms of normalized water
permeability decline rate after 150 h and 370 h operation, respectively. Membrane autopsy results
indicated that the fouling layer formed under the influence of EMF was loose with a low density and
was easily removed by hydraulic flushing
Removal of Escherichia Coli from Domestic Wastewater Using Electrocoagulation
ABSTRACT
The objective of this study was to evaluate the efficiency of electrocoagulation in the removal of Escherichia coli from domestic and urban wastewaters and to determine the effects of the main operational parameters on the process. An electrocoagulation reactor with aluminum and iron electrodes was built for this purpose. A factorial design was applied, where amperage, treatment time, and pH were considered as the factors and E. coli percent removal was the response variable. After 20 min of treatment, >97% removal efficiency was achieved. The highest E. coli removal efficiency achieved was 99.9% at a neutral pH of 7, amperage of 3 A, and treatment time of 60 min. However, the removal efficiency of close to 99% was also achieved at natural wastewater pH of 8.5. The statistical analyses showed that the three tested factors significantly affected the E. coli removal percentage (p < 0.05). These results indicate that electrocoagulation has a high disinfection power in a primary reactor in removing water con[1]taminants as well as simultaneously removing pathogenic microorganisms when compared to biological treatment processes. This represents an additional benefit, because it will considerably reduce the use of chlorine during the final disinfection stage.
Removal of Escherichia Coli from Domestic Wastewater Using Electrocoagulation
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The objective of this study was to evaluate the efficiency of electrocoagulation in the removal of Escherichia coli from domestic and urban wastewaters and to determine the effects of the main operational parameters on the process. An electrocoagulation reactor with aluminum and iron electrodes was built for this purpose. A factorial design was applied, where amperage, treatment time, and pH were considered as the factors and E. coli percent removal was the response variable. After 20 min of treatment, >97% removal efficiency was achieved. The highest E. coli removal efficiency achieved was 99.9% at a neutral pH of 7, amperage of 3 A, and treatment time of 60 min. However, the removal efficiency of close to 99% was also achieved at natural wastewater pH of 8.5. The statistical analyses showed that the three tested factors significantly affected the E. coli removal percentage (p < 0.05). These results indicate that electrocoagulation has a high disinfection power in a primary reactor in removing water con[1]taminants as well as simultaneously removing pathogenic microorganisms when compared to biological treatment processes. This represents an additional benefit, because it will considerably reduce the use of chlorine during the final disinfection stage.
Correlation Between BOD5 and COD for Al- Diwaniyah Wastewater Treatment Plants to Obtain The Biodigrability Indices
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The present study aims to establish an empirical correlation between biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) of the sewage flowing in Al-Diwaniyah wastewater treatment plant. The strength of the wastewater entering the plant varied from medium to high. High concentrations of BOD5 and COD in the effluent were obtained due to the poor performance of the plant. This was observed from the BOD5 /COD ratios that did not confirm with the typical ratios for the treated sewage. Regression equations for BOD5 and COD removal percentages were suggested which can be used to evaluate rapid effluent assessment after the treatment processes or optimal process control to improve the performance of wastewater treatment plants. The average Biodegradability indices (B.I) of Al-Diwaniyah wastewater plants was found to be 0.69. The equations relating the percentage removal of BOD5(y) with influent BOD5(x), y= 0.044x + 80.66 and the percentage removal of COD (y) with influent COD (x), y= 0.045x + 55.15 were found with high correlation R2 =0.72 and 0.86 respectively. Keywords: BOD5, COD, BOD5/COD ratio, Biodegradability indices, BOD5 and COD correlations
Correlation Between BOD5 and COD for Al- Diwaniyah Wastewater Treatment Plants to Obtain The Biodigrability Indices
ABSTRACT
The present study aims to establish an empirical correlation between biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) of the sewage flowing in Al-Diwaniyah wastewater treatment plant. The strength of the wastewater entering the plant varied from medium to high. High concentrations of BOD5 and COD in the effluent were obtained due to the poor performance of the plant. This was observed from the BOD5 /COD ratios that did not confirm with the typical ratios for the treated sewage. Regression equations for BOD5 and COD removal percentages were suggested which can be used to evaluate rapid effluent assessment after the treatment processes or optimal process control to improve the performance of wastewater treatment plants. The average Biodegradability indices (B.I) of Al-Diwaniyah wastewater plants was found to be 0.69. The equations relating the percentage removal of BOD5(y) with influent BOD5(x), y= 0.044x + 80.66 and the percentage removal of COD (y) with influent COD (x), y= 0.045x + 55.15 were found with high correlation R2 =0.72 and 0.86 respectively. Keywords: BOD5, COD, BOD5/COD ratio, Biodegradability indices, BOD5 and COD correlations
Desalination: From Ancient To Present And Future
Abstract:
Water is life, and without water, there would be no civilizations and a vacant Earth. Water is considered an abundant natural resource on the earth. Water covers 3/4 of the surface. However, 97% of the available water on the earth is salty oceanic water, and only a tiny fraction (3%) is freshwater. This small portion of the available water supplies the needs of humans and animals. However, freshwater exists in underground, rivers, and lakes and is insufficient to cover all the world’s water demands. Thus, water saving, water reuse, rainwater harvesting, stormwater utilization, and desalination are critical for maintaining water supplies for the future of humanity. Desalination has a long history spanning centuries from ancient times to the present. In the last two decades, desalination has been rapidly expanding to meet water needs in stressed water regions of the world. Yet, there are still some problems with its implementation in several areas of the world. This review provides a comprehensive assessment of the history of desalination for wiser and smarter water extraction and uses to sustain and support the water needs of the earth’s inhabitants.
Desalination: From Ancient To Present And Future
Abstract:
Water is life, and without water, there would be no civilizations and a vacant Earth. Water is considered an abundant natural resource on the earth. Water covers 3/4 of the surface. However, 97% of the available water on the earth is salty oceanic water, and only a tiny fraction (3%) is freshwater. This small portion of the available water supplies the needs of humans and animals. However, freshwater exists in underground, rivers, and lakes and is insufficient to cover all the world’s water demands. Thus, water saving, water reuse, rainwater harvesting, stormwater utilization, and desalination are critical for maintaining water supplies for the future of humanity. Desalination has a long history spanning centuries from ancient times to the present. In the last two decades, desalination has been rapidly expanding to meet water needs in stressed water regions of the world. Yet, there are still some problems with its implementation in several areas of the world. This review provides a comprehensive assessment of the history of desalination for wiser and smarter water extraction and uses to sustain and support the water needs of the earth’s inhabitants.
Correlating BOD5 and COD of Sewage in Wastewater Treatment Plants Case Study Al- Diwaniyah WWTP in Iraq
ABSTRACT
This study aims to establish an empirical correlation between biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) of the sewage flowing in Al-Diwaniyah wastewater treatment plant. The strength of the wastewater entering the plant varied from medium to high. High concentrations of BOD5 and COD in the effluent were obtained due to the poor performance of the plant. This was observed from the BOD5 /COD ratios that did not confirm with the typical ratios for the treated sewage. To improve the performance of this plant, regression equations for BOD5 and COD removal percentages were suggested which can be used to facilitate rapid effluent assessment or optimal process control. The equations relating the percentage removal of BOD5(y) with influent BOD5(x), y= 0.044x + 80.66 and the percentage removal of COD (y) with influent COD (x), y= 0.045x + 55.15 were found with high correlation R2 =0.72 and 0.86 respectively. Key words: Sewage treatment, BOD5, COD, BOD5/COD ratio, BOD5&COD correlations
Correlating BOD5 and COD of Sewage in Wastewater Treatment Plants Case Study Al- Diwaniyah WWTP in Iraq
ABSTRACT
This study aims to establish an empirical correlation between biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) of the sewage flowing in Al-Diwaniyah wastewater treatment plant. The strength of the wastewater entering the plant varied from medium to high. High concentrations of BOD5 and COD in the effluent were obtained due to the poor performance of the plant. This was observed from the BOD5 /COD ratios that did not confirm with the typical ratios for the treated sewage. To improve the performance of this plant, regression equations for BOD5 and COD removal percentages were suggested which can be used to facilitate rapid effluent assessment or optimal process control. The equations relating the percentage removal of BOD5(y) with influent BOD5(x), y= 0.044x + 80.66 and the percentage removal of COD (y) with influent COD (x), y= 0.045x + 55.15 were found with high correlation R2 =0.72 and 0.86 respectively. Key words: Sewage treatment, BOD5, COD, BOD5/COD ratio, BOD5&COD correlations
A Review of the Water Desalination Technologies
Abstract: Desalination is commonly adopted nowadays to overcome the freshwater scarcity in
some areas of the world if brackish water or salt water is available. Different kinds of technologies
have been proposed in the last century. In this paper, the state of the mainstream solutions is
reported, showing the current commercial technologies like reverse osmosis (RO), Multi-Stages Flash
desalination (MSF) and Multi-Effect Distillation (MED), and the new frontiers of the research with
the aim of exploiting renewable sources such as wind, solar and biomass energy. In these cases,
seawater treatment plants are the same as traditional ones, with the only difference being that they
use a renewable energy source. Thus, classifications are firstly introduced, considering the working
principles, the main energy input required for the treatment, and the potential for coupling with
renewable energy sources. Each technology is described in detail, showing how the process works
and reporting some data on the state of development. Finally, a statistical analysis is given concerning
the spread of the various technologies across the world and which of them are most exploited. In this
section, an important energy and exergy analysis is also addressed to quantify energy losses.
A Review of the Water Desalination Technologies
Abstract: Desalination is commonly adopted nowadays to overcome the freshwater scarcity in
some areas of the world if brackish water or salt water is available. Different kinds of technologies
have been proposed in the last century. In this paper, the state of the mainstream solutions is
reported, showing the current commercial technologies like reverse osmosis (RO), Multi-Stages Flash
desalination (MSF) and Multi-Effect Distillation (MED), and the new frontiers of the research with
the aim of exploiting renewable sources such as wind, solar and biomass energy. In these cases,
seawater treatment plants are the same as traditional ones, with the only difference being that they
use a renewable energy source. Thus, classifications are firstly introduced, considering the working
principles, the main energy input required for the treatment, and the potential for coupling with
renewable energy sources. Each technology is described in detail, showing how the process works
and reporting some data on the state of development. Finally, a statistical analysis is given concerning
the spread of the various technologies across the world and which of them are most exploited. In this
section, an important energy and exergy analysis is also addressed to quantify energy losses.
Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures
Biofouling is a critical issue in membrane water and wastewater treatment as it greatly compromises the efficiency of the treatment processes. It is difficult to control, and significant economic resources have been dedicated to the development of effective biofouling monitoring and control strategies. This paper highlights the underlying causes of membrane biofouling and provides a review on recent developments of potential monitoring and control methods in water and wastewater treatment with the aim of identifying the remaining issues and challenges in this area.
Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures
Biofouling is a critical issue in membrane water and wastewater treatment as it greatly compromises the efficiency of the treatment processes. It is difficult to control, and significant economic resources have been dedicated to the development of effective biofouling monitoring and control strategies. This paper highlights the underlying causes of membrane biofouling and provides a review on recent developments of potential monitoring and control methods in water and wastewater treatment with the aim of identifying the remaining issues and challenges in this area.
Applications of Nanotechnology in Wastewater Treatment
Abstract:
Waste water treatment issues have been a growing problems these days. Its treatment is becoming must in this Industrial world. Nanoparticles have a great potential to be used in waste water treatment. Some of the unique characteristics of it having high surface area can be used efficiently for removing toxic metal ions, disease causing microbes, inorganic and organic solutes from water. The different classes of nanomaterials also have the authority to be efficient for water treatment like metal-containing nanoparticles, carbonaceous nanomaterials and zeolites. The review includes recent development in nanotechnology for water and wastewater treatment. The paper covers nanomaterials that enables the applications, advantages and limitations as compared to existing processes. Nanotechnology has led to various efficient ways for treatment of waste water in a more precise and accurate way on both small and large scale.
Applications of Nanotechnology in Wastewater Treatment
Abstract:
Waste water treatment issues have been a growing problems these days. Its treatment is becoming must in this Industrial world. Nanoparticles have a great potential to be used in waste water treatment. Some of the unique characteristics of it having high surface area can be used efficiently for removing toxic metal ions, disease causing microbes, inorganic and organic solutes from water. The different classes of nanomaterials also have the authority to be efficient for water treatment like metal-containing nanoparticles, carbonaceous nanomaterials and zeolites. The review includes recent development in nanotechnology for water and wastewater treatment. The paper covers nanomaterials that enables the applications, advantages and limitations as compared to existing processes. Nanotechnology has led to various efficient ways for treatment of waste water in a more precise and accurate way on both small and large scale.
Nanotechnology in Water Treatment
ABSTRACT Drinking water is unfortunately becoming a rare luxury on our planet.On the other hand, with a trend of population growth, need for water which is essential to life,is becomingbigger every day.Practical application of nanotechnology in saving water worldwide is in using nanoparticles in detection of water pollution and water purification. This knowledge has importance in medicine and public health, so as in environment safety.Possible application areas of nanotechnology in field of purification and treatment of water are in filtration, catalytic and separation processes, ion exchanging, sensitive pollutant detection,etc.Nanotechnology could be the main solution in future fortreatment of surface water,groundwater, and waste water contaminated by toxic metal ions, organic and inorganic solutes, and microorganisms.
Nanotechnology in Water Treatment
ABSTRACT Drinking water is unfortunately becoming a rare luxury on our planet.On the other hand, with a trend of population growth, need for water which is essential to life,is becomingbigger every day.Practical application of nanotechnology in saving water worldwide is in using nanoparticles in detection of water pollution and water purification. This knowledge has importance in medicine and public health, so as in environment safety.Possible application areas of nanotechnology in field of purification and treatment of water are in filtration, catalytic and separation processes, ion exchanging, sensitive pollutant detection,etc.Nanotechnology could be the main solution in future fortreatment of surface water,groundwater, and waste water contaminated by toxic metal ions, organic and inorganic solutes, and microorganisms.
Removal Of Polar Organic Micropollutants By Pilot-Scale Reverse Osmosis Drinking Water Treatment
Abstract : The robustness of reverse osmosis (RO) against polar organic micropollutants (MPs) was investigated in
pilot-scale drinking water treatment. Experiments were carried in hypoxic conditions to treat a raw anaerobic riverbank filtrate spiked with a mixture of thirty model compounds. The chemicals were selected from scientific literature data based on their relevance for the quality of freshwater systems, RO permeate and drinking water. MPs passage and the influence of permeate flux were evaluated with a typical low-pressure RO membrane and quantified by liquid chromatography coupled to high-resolution mass spectrometry. A strong inverse correlation between size and passage of neutral hydrophilic compounds was observed. This correlation was weaker for moderately hydrophobic MPs. Anionic MPs displayed nearly no passage due to electrostatic repulsion with the negatively charged membrane surface,
whereas breakthrough of small cationic MPs could be observed. The passage figures observed for the investigated set of MPs ranged from less than 1%e25%. Statistical analysis was performed to evaluate the relationship between physicochemical properties and passage. The effects of permeate flux were more pronounced for small neutral MPs, which displayed a higher passage after a pressure drop.
Removal Of Polar Organic Micropollutants By Pilot-Scale Reverse Osmosis Drinking Water Treatment
Abstract : The robustness of reverse osmosis (RO) against polar organic micropollutants (MPs) was investigated in
pilot-scale drinking water treatment. Experiments were carried in hypoxic conditions to treat a raw anaerobic riverbank filtrate spiked with a mixture of thirty model compounds. The chemicals were selected from scientific literature data based on their relevance for the quality of freshwater systems, RO permeate and drinking water. MPs passage and the influence of permeate flux were evaluated with a typical low-pressure RO membrane and quantified by liquid chromatography coupled to high-resolution mass spectrometry. A strong inverse correlation between size and passage of neutral hydrophilic compounds was observed. This correlation was weaker for moderately hydrophobic MPs. Anionic MPs displayed nearly no passage due to electrostatic repulsion with the negatively charged membrane surface,
whereas breakthrough of small cationic MPs could be observed. The passage figures observed for the investigated set of MPs ranged from less than 1%e25%. Statistical analysis was performed to evaluate the relationship between physicochemical properties and passage. The effects of permeate flux were more pronounced for small neutral MPs, which displayed a higher passage after a pressure drop.
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