Influence of Stress on Optical Transitions in GaN Nanorods Containing a Single InGaNGaN Quantum Disk
Influence of Stress on Optical Transitions in GaN Nanorods Containing a Single InGaNGaN Quantum Disk
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Removal of Escherichia Coli from Domestic Wastewater Using Electrocoagulation
ABSTRACT
The objective of this study was to evaluate the efficiency of electrocoagulation in the removal of Escherichia coli from domestic and urban wastewaters and to determine the effects of the main operational parameters on the process. An electrocoagulation reactor with aluminum and iron electrodes was built for this purpose. A factorial design was applied, where amperage, treatment time, and pH were considered as the factors and E. coli percent removal was the response variable. After 20 min of treatment, >97% removal efficiency was achieved. The highest E. coli removal efficiency achieved was 99.9% at a neutral pH of 7, amperage of 3 A, and treatment time of 60 min. However, the removal efficiency of close to 99% was also achieved at natural wastewater pH of 8.5. The statistical analyses showed that the three tested factors significantly affected the E. coli removal percentage (p < 0.05). These results indicate that electrocoagulation has a high disinfection power in a primary reactor in removing water con[1]taminants as well as simultaneously removing pathogenic microorganisms when compared to biological treatment processes. This represents an additional benefit, because it will considerably reduce the use of chlorine during the final disinfection stage.
Removal of Escherichia Coli from Domestic Wastewater Using Electrocoagulation
ABSTRACT
The objective of this study was to evaluate the efficiency of electrocoagulation in the removal of Escherichia coli from domestic and urban wastewaters and to determine the effects of the main operational parameters on the process. An electrocoagulation reactor with aluminum and iron electrodes was built for this purpose. A factorial design was applied, where amperage, treatment time, and pH were considered as the factors and E. coli percent removal was the response variable. After 20 min of treatment, >97% removal efficiency was achieved. The highest E. coli removal efficiency achieved was 99.9% at a neutral pH of 7, amperage of 3 A, and treatment time of 60 min. However, the removal efficiency of close to 99% was also achieved at natural wastewater pH of 8.5. The statistical analyses showed that the three tested factors significantly affected the E. coli removal percentage (p < 0.05). These results indicate that electrocoagulation has a high disinfection power in a primary reactor in removing water con[1]taminants as well as simultaneously removing pathogenic microorganisms when compared to biological treatment processes. This represents an additional benefit, because it will considerably reduce the use of chlorine during the final disinfection stage.
Comparison of Wastewater Treatment Using Activated Carbon from Bamboo and Oil Palm
Abstract
Developing country causes growth of industries sectors. Despite that industrial sectors releases massive amount of waste water into the environment. At the same time, the increasing number of vehicles in Malaysia promotes the development of automobile workshop that produces huge amount of wastewater as well. Wastewater contains high level of suspended total solids and leave untreated. For instance oil, grease, dyestuff, chromium, phosphate in washing products and colouring, as well as heavy metals such as lead, cadmium, barium and others potential metals. All these hazardous wastes directly pollute the environment especially the groundwater and harm the ecosystem. In order to minimize and reduce the impact to the environment, the wastewater needed to be treated using technology such as permeable reactive barrier (PRB). Activated carbon is one of the PRB utilised. It is a compromised material for treatment of wastewater where there are varieties of sources to produce activated carbon. Malaysia as an active agricultural country, massive amount of agriculture wastes can be turned into activated carbon. They are two methods used to produce activated carbon, namely furnace heat processing and microwave processing. The usage of furnace and microwave instruments can produce different quality of activated carbon due to different mechanism involves. Furnace heat processing transferred the heat from external to the internal but microwave processing is vice versa. In this article, a brief overview of activated carbon usage for wastewater treatment is highlighted.
Comparison of Wastewater Treatment Using Activated Carbon from Bamboo and Oil Palm
Abstract
Developing country causes growth of industries sectors. Despite that industrial sectors releases massive amount of waste water into the environment. At the same time, the increasing number of vehicles in Malaysia promotes the development of automobile workshop that produces huge amount of wastewater as well. Wastewater contains high level of suspended total solids and leave untreated. For instance oil, grease, dyestuff, chromium, phosphate in washing products and colouring, as well as heavy metals such as lead, cadmium, barium and others potential metals. All these hazardous wastes directly pollute the environment especially the groundwater and harm the ecosystem. In order to minimize and reduce the impact to the environment, the wastewater needed to be treated using technology such as permeable reactive barrier (PRB). Activated carbon is one of the PRB utilised. It is a compromised material for treatment of wastewater where there are varieties of sources to produce activated carbon. Malaysia as an active agricultural country, massive amount of agriculture wastes can be turned into activated carbon. They are two methods used to produce activated carbon, namely furnace heat processing and microwave processing. The usage of furnace and microwave instruments can produce different quality of activated carbon due to different mechanism involves. Furnace heat processing transferred the heat from external to the internal but microwave processing is vice versa. In this article, a brief overview of activated carbon usage for wastewater treatment is highlighted.
Removal Of Polar Organic Micropollutants By Pilot-Scale Reverse Osmosis Drinking Water Treatment
Abstract : The robustness of reverse osmosis (RO) against polar organic micropollutants (MPs) was investigated in
pilot-scale drinking water treatment. Experiments were carried in hypoxic conditions to treat a raw anaerobic riverbank filtrate spiked with a mixture of thirty model compounds. The chemicals were selected from scientific literature data based on their relevance for the quality of freshwater systems, RO permeate and drinking water. MPs passage and the influence of permeate flux were evaluated with a typical low-pressure RO membrane and quantified by liquid chromatography coupled to high-resolution mass spectrometry. A strong inverse correlation between size and passage of neutral hydrophilic compounds was observed. This correlation was weaker for moderately hydrophobic MPs. Anionic MPs displayed nearly no passage due to electrostatic repulsion with the negatively charged membrane surface,
whereas breakthrough of small cationic MPs could be observed. The passage figures observed for the investigated set of MPs ranged from less than 1%e25%. Statistical analysis was performed to evaluate the relationship between physicochemical properties and passage. The effects of permeate flux were more pronounced for small neutral MPs, which displayed a higher passage after a pressure drop.
Removal Of Polar Organic Micropollutants By Pilot-Scale Reverse Osmosis Drinking Water Treatment
Abstract : The robustness of reverse osmosis (RO) against polar organic micropollutants (MPs) was investigated in
pilot-scale drinking water treatment. Experiments were carried in hypoxic conditions to treat a raw anaerobic riverbank filtrate spiked with a mixture of thirty model compounds. The chemicals were selected from scientific literature data based on their relevance for the quality of freshwater systems, RO permeate and drinking water. MPs passage and the influence of permeate flux were evaluated with a typical low-pressure RO membrane and quantified by liquid chromatography coupled to high-resolution mass spectrometry. A strong inverse correlation between size and passage of neutral hydrophilic compounds was observed. This correlation was weaker for moderately hydrophobic MPs. Anionic MPs displayed nearly no passage due to electrostatic repulsion with the negatively charged membrane surface,
whereas breakthrough of small cationic MPs could be observed. The passage figures observed for the investigated set of MPs ranged from less than 1%e25%. Statistical analysis was performed to evaluate the relationship between physicochemical properties and passage. The effects of permeate flux were more pronounced for small neutral MPs, which displayed a higher passage after a pressure drop.
Analysis of the Flux Performance of Different RO/NF Membranes in the Treatment of Agroindustrial Wastewater by Means of the Boundary Flux Theory
Abstract:
Dynamic membrane system behaviour must be adequately addressed to avoid process unfeasibility. The lack of proper analysis will mean relying on erroneous permeate flux values in the system design, which will lead to quick and/or steady high fouling rates. In this paper, the authors present additional data supporting the boundary flux theory as a helpful tool for membrane engineers to carefully avoid process failures. By fitting the dynamic permeate flux data to the
boundary flux model, it was possible to calculate the β fouling index for the three selected membranes (one nanofiltration (NF) and two reverse osmosis (RO) ones). The dynamic flux given by the low-pressure RO membrane did not follow sub-boundary operating conditions, since a sharp flux loss was measured throughout the whole operating cycle, pinpointing that supra-boundary flux conditions were governing the system. This was supported by the calculated value of the β fouling parameter, which resulted to be in the order of ten times higher for this membrane. However, the values of β→0 for the SC-RO and DK-NF ones, supported by the very low value of the sub-boundary fouling parameter α (0.002 and 0.007 L·h −1·m−2 ·bar−2 , respectively), ensure nearly boundary operating conditions for these membranes.
Analysis of the Flux Performance of Different RO/NF Membranes in the Treatment of Agroindustrial Wastewater by Means of the Boundary Flux Theory
Abstract:
Dynamic membrane system behaviour must be adequately addressed to avoid process unfeasibility. The lack of proper analysis will mean relying on erroneous permeate flux values in the system design, which will lead to quick and/or steady high fouling rates. In this paper, the authors present additional data supporting the boundary flux theory as a helpful tool for membrane engineers to carefully avoid process failures. By fitting the dynamic permeate flux data to the
boundary flux model, it was possible to calculate the β fouling index for the three selected membranes (one nanofiltration (NF) and two reverse osmosis (RO) ones). The dynamic flux given by the low-pressure RO membrane did not follow sub-boundary operating conditions, since a sharp flux loss was measured throughout the whole operating cycle, pinpointing that supra-boundary flux conditions were governing the system. This was supported by the calculated value of the β fouling parameter, which resulted to be in the order of ten times higher for this membrane. However, the values of β→0 for the SC-RO and DK-NF ones, supported by the very low value of the sub-boundary fouling parameter α (0.002 and 0.007 L·h −1·m−2 ·bar−2 , respectively), ensure nearly boundary operating conditions for these membranes.
Water Desalination Using Solar Thermal Collectors Enhanced by Nanofluids
Introduction
In the future, the world is confronted with energy and freshwater shortage. Desalination of brackish or seawater is one of the most important ways to solve the water scarcity issue [1, 2]. The use of solar energy or waste heat sources is acceptable for water-producing systems of such a small size [3–5]. The relevancy of nanomaterials is to realize the best attainable properties within the smallest possible loadings through homogenized distribution and stable suspension of these nanoparticles[6–11]. Often, heat transfer improvement in solar collectors is one of the basic problems in energy saving, compact designs, and different operating temperatures. Researchers also investigated the multiwalled carbon nanotubes (MWCNTs) and water nanofluids with a pH of 3.5, 6.5, and 9.5, and Triton X-100 as a surfactant (0.2 wt %) using flat-plate solar collectors. It was found that the nanofluids have better heat transfer performance in acidic and alkaline water due to the influence of the isoelectric point. The higher efficiency (67 %) was obtained at pH 9.5 and 3.5 with a water flow rate of 0.0333 kg s–1. A stable nanofluid based on ethylene glycol-containing nanosheets of graphene oxide was prepared by Yu et al. [12]. The improvement in thermal conductivity relies strongly on the volume fraction of the nanosheet of graphene oxide and increases with higher nanoparticle loading. The heat efficiency was enhanced up to 61.0 % using a nanosheet loading of 5.0 vol %. For seven days, the thermal conductivity of the fluids remained almost constant, which suggests their high stability. In the measured temperature range, the enhancement value was independent of the temperature. Peyghambarzadeh et al. [13, 14] studied force convection techniques in an excessively base water nanofluid, which was experimentally compared to water in a vehicle heat exchanger with different nanofluid loadings. It was experimentally investigated to improve the rate of heat transfer. The variable effect of the inlet temperature of the fluid in the heat exchanger on the heat transfer coefficient was evaluated. The findings showed that the incremental fluid circulation rate would increase the output rate of heat transfer, while the temperature of the fluid entering the heat exchanger had negligible effects. Meanwhile, water nanofluid subservience at low-volume loadings would increase the heat transfer rate efficiency by approximately 44 % compared to water
Water Desalination Using Solar Thermal Collectors Enhanced by Nanofluids
Introduction
In the future, the world is confronted with energy and freshwater shortage. Desalination of brackish or seawater is one of the most important ways to solve the water scarcity issue [1, 2]. The use of solar energy or waste heat sources is acceptable for water-producing systems of such a small size [3–5]. The relevancy of nanomaterials is to realize the best attainable properties within the smallest possible loadings through homogenized distribution and stable suspension of these nanoparticles[6–11]. Often, heat transfer improvement in solar collectors is one of the basic problems in energy saving, compact designs, and different operating temperatures. Researchers also investigated the multiwalled carbon nanotubes (MWCNTs) and water nanofluids with a pH of 3.5, 6.5, and 9.5, and Triton X-100 as a surfactant (0.2 wt %) using flat-plate solar collectors. It was found that the nanofluids have better heat transfer performance in acidic and alkaline water due to the influence of the isoelectric point. The higher efficiency (67 %) was obtained at pH 9.5 and 3.5 with a water flow rate of 0.0333 kg s–1. A stable nanofluid based on ethylene glycol-containing nanosheets of graphene oxide was prepared by Yu et al. [12]. The improvement in thermal conductivity relies strongly on the volume fraction of the nanosheet of graphene oxide and increases with higher nanoparticle loading. The heat efficiency was enhanced up to 61.0 % using a nanosheet loading of 5.0 vol %. For seven days, the thermal conductivity of the fluids remained almost constant, which suggests their high stability. In the measured temperature range, the enhancement value was independent of the temperature. Peyghambarzadeh et al. [13, 14] studied force convection techniques in an excessively base water nanofluid, which was experimentally compared to water in a vehicle heat exchanger with different nanofluid loadings. It was experimentally investigated to improve the rate of heat transfer. The variable effect of the inlet temperature of the fluid in the heat exchanger on the heat transfer coefficient was evaluated. The findings showed that the incremental fluid circulation rate would increase the output rate of heat transfer, while the temperature of the fluid entering the heat exchanger had negligible effects. Meanwhile, water nanofluid subservience at low-volume loadings would increase the heat transfer rate efficiency by approximately 44 % compared to water
Emerging desalination technologies for water treatment: A critical review
Abstract:
In this paper, a review of emerging desalination technologies is presented. Several technologies for desalination of municipal and industrial wastewater have been proposed and evaluated, but only certain technologies have been commercialized or are close to commercialization. This review consists of membrane-based, thermal-based and alternative technologies. Membranes based on incorporation of nanoparticles, carbon nanotubes or graphene-based ones show promise as innovative desalination technologies with superior performance in terms of water permeability and salt rejection. However, only nanocomposite membranes have been commercialized while others are still under fundamental developmental stages. Among the thermal-based technologies, membrane
distillation and adsorption desalination show the most promise for enhanced performance with the availability of a waste heat source. Several alternative technologies have also been developed recently; those based on capacitive deionization have shown considerable improvements in their salt removal capacity and feed water recovery. In the same category, microbial desalination cells have been shown to desalinate high salinity water without any external energy source, but to date, scale up of the process has not been methodically evaluated. In this paper, advantages and drawbacks of each technology is discussed along with a comparison of performance, water quality and energy consumption.
Emerging desalination technologies for water treatment: A critical review
Abstract:
In this paper, a review of emerging desalination technologies is presented. Several technologies for desalination of municipal and industrial wastewater have been proposed and evaluated, but only certain technologies have been commercialized or are close to commercialization. This review consists of membrane-based, thermal-based and alternative technologies. Membranes based on incorporation of nanoparticles, carbon nanotubes or graphene-based ones show promise as innovative desalination technologies with superior performance in terms of water permeability and salt rejection. However, only nanocomposite membranes have been commercialized while others are still under fundamental developmental stages. Among the thermal-based technologies, membrane
distillation and adsorption desalination show the most promise for enhanced performance with the availability of a waste heat source. Several alternative technologies have also been developed recently; those based on capacitive deionization have shown considerable improvements in their salt removal capacity and feed water recovery. In the same category, microbial desalination cells have been shown to desalinate high salinity water without any external energy source, but to date, scale up of the process has not been methodically evaluated. In this paper, advantages and drawbacks of each technology is discussed along with a comparison of performance, water quality and energy consumption.
Adsorption of Heavy Metals from Multi-Metal Aqueous Solution by Sunflower Plant Biomass-Based Carbons
Abstract
This study reports the competitive adsorption
of Ni(II), Cd(II) and Cr(VI) onto sunflower waste biomass
carbons, viz. sunflower head carbon and sunflower stem
carbon from multi-metal aqueous solution.
Adsorption of Heavy Metals from Multi-Metal Aqueous Solution by Sunflower Plant Biomass-Based Carbons
Abstract
This study reports the competitive adsorption
of Ni(II), Cd(II) and Cr(VI) onto sunflower waste biomass
carbons, viz. sunflower head carbon and sunflower stem
carbon from multi-metal aqueous solution.
Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures
Biofouling is a critical issue in membrane water and wastewater treatment as it greatly compromises the efficiency of the treatment processes. It is difficult to control, and significant economic resources have been dedicated to the development of effective biofouling monitoring and control strategies. This paper highlights the underlying causes of membrane biofouling and provides a review on recent developments of potential monitoring and control methods in water and wastewater treatment with the aim of identifying the remaining issues and challenges in this area.
Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures
Biofouling is a critical issue in membrane water and wastewater treatment as it greatly compromises the efficiency of the treatment processes. It is difficult to control, and significant economic resources have been dedicated to the development of effective biofouling monitoring and control strategies. This paper highlights the underlying causes of membrane biofouling and provides a review on recent developments of potential monitoring and control methods in water and wastewater treatment with the aim of identifying the remaining issues and challenges in this area.
Engineered Nanomaterials for Water Treatment and Remediation
Water is one of the world’s most abundant resources, but less than 1% of the global supply of water is available and safe for human consumption [1]. According to the World Health Organization, over 760 million people were without adequate drinking water supply in 2011 [2]. Where it is available, the cost of potable water is rising due to increasing energy costs, growing populations, and climatic or other environmental issues [1,3]. In addition, an increasing number of drinking water sources are showing evidence of contamination, especially by emerging pollutants like pharmaceuticals and personal care products [4,5]. Many traditional water and wastewater treatment methods do not effectively remove these emerging contaminants, and/or are not capable of removing enough to meet increasingly stringent water quality standards [5,6]. Contamination of surface waters also constitutes a risk to water supplies because pollutants may penetrate into aquifers, where they can be transported to drinking water sources.
Engineered Nanomaterials for Water Treatment and Remediation
Water is one of the world’s most abundant resources, but less than 1% of the global supply of water is available and safe for human consumption [1]. According to the World Health Organization, over 760 million people were without adequate drinking water supply in 2011 [2]. Where it is available, the cost of potable water is rising due to increasing energy costs, growing populations, and climatic or other environmental issues [1,3]. In addition, an increasing number of drinking water sources are showing evidence of contamination, especially by emerging pollutants like pharmaceuticals and personal care products [4,5]. Many traditional water and wastewater treatment methods do not effectively remove these emerging contaminants, and/or are not capable of removing enough to meet increasingly stringent water quality standards [5,6]. Contamination of surface waters also constitutes a risk to water supplies because pollutants may penetrate into aquifers, where they can be transported to drinking water sources.
A Review of the Water Desalination Technologies
Abstract: Desalination is commonly adopted nowadays to overcome the freshwater scarcity in
some areas of the world if brackish water or salt water is available. Different kinds of technologies
have been proposed in the last century. In this paper, the state of the mainstream solutions is
reported, showing the current commercial technologies like reverse osmosis (RO), Multi-Stages Flash
desalination (MSF) and Multi-Effect Distillation (MED), and the new frontiers of the research with
the aim of exploiting renewable sources such as wind, solar and biomass energy. In these cases,
seawater treatment plants are the same as traditional ones, with the only difference being that they
use a renewable energy source. Thus, classifications are firstly introduced, considering the working
principles, the main energy input required for the treatment, and the potential for coupling with
renewable energy sources. Each technology is described in detail, showing how the process works
and reporting some data on the state of development. Finally, a statistical analysis is given concerning
the spread of the various technologies across the world and which of them are most exploited. In this
section, an important energy and exergy analysis is also addressed to quantify energy losses.
A Review of the Water Desalination Technologies
Abstract: Desalination is commonly adopted nowadays to overcome the freshwater scarcity in
some areas of the world if brackish water or salt water is available. Different kinds of technologies
have been proposed in the last century. In this paper, the state of the mainstream solutions is
reported, showing the current commercial technologies like reverse osmosis (RO), Multi-Stages Flash
desalination (MSF) and Multi-Effect Distillation (MED), and the new frontiers of the research with
the aim of exploiting renewable sources such as wind, solar and biomass energy. In these cases,
seawater treatment plants are the same as traditional ones, with the only difference being that they
use a renewable energy source. Thus, classifications are firstly introduced, considering the working
principles, the main energy input required for the treatment, and the potential for coupling with
renewable energy sources. Each technology is described in detail, showing how the process works
and reporting some data on the state of development. Finally, a statistical analysis is given concerning
the spread of the various technologies across the world and which of them are most exploited. In this
section, an important energy and exergy analysis is also addressed to quantify energy losses.
A Review of Reverse Osmosis Membrane Fouling and Control Strategies
Introduction
This paper reviews membrane contamination and dirt Control strategies, focusing on the latest developments.
The first goal From this paper is to illustrate the types of dirt.
The second goal is To discuss the latest pollution mitigation strategies, including pre-treatment, monitoring, cleaning, and surface modification as well as updates.
A Review of Reverse Osmosis Membrane Fouling and Control Strategies
Introduction
This paper reviews membrane contamination and dirt Control strategies, focusing on the latest developments.
The first goal From this paper is to illustrate the types of dirt.
The second goal is To discuss the latest pollution mitigation strategies, including pre-treatment, monitoring, cleaning, and surface modification as well as updates.
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