LC-MS Analysis Of Basic Pharmaceuticals (Beta-Blockers And Anti-Ulcer Agents) In Wastewater And Surface Water
Source: https://www.sciencedirect.com/journal/trac-trends-in-analytical-chemistry
Author: M. Dolores Hernando, M. Jose´Go´mez, Ana Aguera, Amadeo R. Ferna´ndez-Alba
Most current research concerned with pharmaceuticals in the environment has been in the development of sensitive and selective analytical methods able to determine pharmaceutical residues in different environmental compartments. Since the first findings of clofibric acid, ibuprofen, nicotine and caffeine in natural water and wastewater in Kansas City and in the Berlin area, several monitoring studies have been carried out to evaluate their occurrence in the environment.
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Fouling and Cleaning Characteristics of Reverse Osmosis (RO) Membranes
Abstract:
This work deals with fouling and successive cleaning of RO membrane fouled by an organic foulant, sodium alginate using a laboratory-scale cross flow test unit. First, spiral-wound RO membrane was fouled with sodium alginate solution up to 10% and 15%, respectively at an applied pressure of 1380 kPa with flow rate of 10 lit/min. An anionic surfactant, sodium dodecyl sulfate (SDS) was used as a chemical cleaning agent for cleaning of RO membrane. The effect of cleaning chemical dose and cross-flow velocity on the membrane chemical cleaning duration to achieve 100% cleaning efficiency (i.e., to get original water flux) was also investigated. As the SDS concentration increases, the membrane chemical cleaning time decreases due to increase in the solubility of the foulant (when the surface tension decreases by an increase in the SDS concentration). Furthermore, the membrane chemical cleaning time decreases with increasing cross-flow velocity of the cleaning chemical solution (SDS). Higher cross-flow velocity enhances the turbulence at the fouling layer and hence the mass transfer of the foulant from the fouling layer to the bulk solution is improved, then the SDS has weakened the structural integrity of the fouling layer. It is observed that better cleaning is occurred with higher concentration of SDS and flow rate. The obtained results clearly reveal that SDS cleaning is proved to be an efficient cleaning method for RO membranes fouled with organic foulant.
Fouling and Cleaning Characteristics of Reverse Osmosis (RO) Membranes
Abstract:
This work deals with fouling and successive cleaning of RO membrane fouled by an organic foulant, sodium alginate using a laboratory-scale cross flow test unit. First, spiral-wound RO membrane was fouled with sodium alginate solution up to 10% and 15%, respectively at an applied pressure of 1380 kPa with flow rate of 10 lit/min. An anionic surfactant, sodium dodecyl sulfate (SDS) was used as a chemical cleaning agent for cleaning of RO membrane. The effect of cleaning chemical dose and cross-flow velocity on the membrane chemical cleaning duration to achieve 100% cleaning efficiency (i.e., to get original water flux) was also investigated. As the SDS concentration increases, the membrane chemical cleaning time decreases due to increase in the solubility of the foulant (when the surface tension decreases by an increase in the SDS concentration). Furthermore, the membrane chemical cleaning time decreases with increasing cross-flow velocity of the cleaning chemical solution (SDS). Higher cross-flow velocity enhances the turbulence at the fouling layer and hence the mass transfer of the foulant from the fouling layer to the bulk solution is improved, then the SDS has weakened the structural integrity of the fouling layer. It is observed that better cleaning is occurred with higher concentration of SDS and flow rate. The obtained results clearly reveal that SDS cleaning is proved to be an efficient cleaning method for RO membranes fouled with organic foulant.
A Review of Reverse Osmosis Membrane Fouling and Control Strategies
Introduction
This paper reviews membrane contamination and dirt Control strategies, focusing on the latest developments.
The first goal From this paper is to illustrate the types of dirt.
The second goal is To discuss the latest pollution mitigation strategies, including pre-treatment, monitoring, cleaning, and surface modification as well as updates.
A Review of Reverse Osmosis Membrane Fouling and Control Strategies
Introduction
This paper reviews membrane contamination and dirt Control strategies, focusing on the latest developments.
The first goal From this paper is to illustrate the types of dirt.
The second goal is To discuss the latest pollution mitigation strategies, including pre-treatment, monitoring, cleaning, and surface modification as well as updates.
Applications of Nanotechnology in Wastewater Treatment
Abstract:
Waste water treatment issues have been a growing problems these days. Its treatment is becoming must in this Industrial world. Nanoparticles have a great potential to be used in waste water treatment. Some of the unique characteristics of it having high surface area can be used efficiently for removing toxic metal ions, disease causing microbes, inorganic and organic solutes from water. The different classes of nanomaterials also have the authority to be efficient for water treatment like metal-containing nanoparticles, carbonaceous nanomaterials and zeolites. The review includes recent development in nanotechnology for water and wastewater treatment. The paper covers nanomaterials that enables the applications, advantages and limitations as compared to existing processes. Nanotechnology has led to various efficient ways for treatment of waste water in a more precise and accurate way on both small and large scale.
Applications of Nanotechnology in Wastewater Treatment
Abstract:
Waste water treatment issues have been a growing problems these days. Its treatment is becoming must in this Industrial world. Nanoparticles have a great potential to be used in waste water treatment. Some of the unique characteristics of it having high surface area can be used efficiently for removing toxic metal ions, disease causing microbes, inorganic and organic solutes from water. The different classes of nanomaterials also have the authority to be efficient for water treatment like metal-containing nanoparticles, carbonaceous nanomaterials and zeolites. The review includes recent development in nanotechnology for water and wastewater treatment. The paper covers nanomaterials that enables the applications, advantages and limitations as compared to existing processes. Nanotechnology has led to various efficient ways for treatment of waste water in a more precise and accurate way on both small and large scale.
Water Desalination Using Solar Thermal Collectors Enhanced by Nanofluids
Introduction
In the future, the world is confronted with energy and freshwater shortage. Desalination of brackish or seawater is one of the most important ways to solve the water scarcity issue [1, 2]. The use of solar energy or waste heat sources is acceptable for water-producing systems of such a small size [3–5]. The relevancy of nanomaterials is to realize the best attainable properties within the smallest possible loadings through homogenized distribution and stable suspension of these nanoparticles[6–11]. Often, heat transfer improvement in solar collectors is one of the basic problems in energy saving, compact designs, and different operating temperatures. Researchers also investigated the multiwalled carbon nanotubes (MWCNTs) and water nanofluids with a pH of 3.5, 6.5, and 9.5, and Triton X-100 as a surfactant (0.2 wt %) using flat-plate solar collectors. It was found that the nanofluids have better heat transfer performance in acidic and alkaline water due to the influence of the isoelectric point. The higher efficiency (67 %) was obtained at pH 9.5 and 3.5 with a water flow rate of 0.0333 kg s–1. A stable nanofluid based on ethylene glycol-containing nanosheets of graphene oxide was prepared by Yu et al. [12]. The improvement in thermal conductivity relies strongly on the volume fraction of the nanosheet of graphene oxide and increases with higher nanoparticle loading. The heat efficiency was enhanced up to 61.0 % using a nanosheet loading of 5.0 vol %. For seven days, the thermal conductivity of the fluids remained almost constant, which suggests their high stability. In the measured temperature range, the enhancement value was independent of the temperature. Peyghambarzadeh et al. [13, 14] studied force convection techniques in an excessively base water nanofluid, which was experimentally compared to water in a vehicle heat exchanger with different nanofluid loadings. It was experimentally investigated to improve the rate of heat transfer. The variable effect of the inlet temperature of the fluid in the heat exchanger on the heat transfer coefficient was evaluated. The findings showed that the incremental fluid circulation rate would increase the output rate of heat transfer, while the temperature of the fluid entering the heat exchanger had negligible effects. Meanwhile, water nanofluid subservience at low-volume loadings would increase the heat transfer rate efficiency by approximately 44 % compared to water
Water Desalination Using Solar Thermal Collectors Enhanced by Nanofluids
Introduction
In the future, the world is confronted with energy and freshwater shortage. Desalination of brackish or seawater is one of the most important ways to solve the water scarcity issue [1, 2]. The use of solar energy or waste heat sources is acceptable for water-producing systems of such a small size [3–5]. The relevancy of nanomaterials is to realize the best attainable properties within the smallest possible loadings through homogenized distribution and stable suspension of these nanoparticles[6–11]. Often, heat transfer improvement in solar collectors is one of the basic problems in energy saving, compact designs, and different operating temperatures. Researchers also investigated the multiwalled carbon nanotubes (MWCNTs) and water nanofluids with a pH of 3.5, 6.5, and 9.5, and Triton X-100 as a surfactant (0.2 wt %) using flat-plate solar collectors. It was found that the nanofluids have better heat transfer performance in acidic and alkaline water due to the influence of the isoelectric point. The higher efficiency (67 %) was obtained at pH 9.5 and 3.5 with a water flow rate of 0.0333 kg s–1. A stable nanofluid based on ethylene glycol-containing nanosheets of graphene oxide was prepared by Yu et al. [12]. The improvement in thermal conductivity relies strongly on the volume fraction of the nanosheet of graphene oxide and increases with higher nanoparticle loading. The heat efficiency was enhanced up to 61.0 % using a nanosheet loading of 5.0 vol %. For seven days, the thermal conductivity of the fluids remained almost constant, which suggests their high stability. In the measured temperature range, the enhancement value was independent of the temperature. Peyghambarzadeh et al. [13, 14] studied force convection techniques in an excessively base water nanofluid, which was experimentally compared to water in a vehicle heat exchanger with different nanofluid loadings. It was experimentally investigated to improve the rate of heat transfer. The variable effect of the inlet temperature of the fluid in the heat exchanger on the heat transfer coefficient was evaluated. The findings showed that the incremental fluid circulation rate would increase the output rate of heat transfer, while the temperature of the fluid entering the heat exchanger had negligible effects. Meanwhile, water nanofluid subservience at low-volume loadings would increase the heat transfer rate efficiency by approximately 44 % compared to water
Engineered Nanomaterials for Water Treatment and Remediation
Water is one of the world’s most abundant resources, but less than 1% of the global supply of water is available and safe for human consumption [1]. According to the World Health Organization, over 760 million people were without adequate drinking water supply in 2011 [2]. Where it is available, the cost of potable water is rising due to increasing energy costs, growing populations, and climatic or other environmental issues [1,3]. In addition, an increasing number of drinking water sources are showing evidence of contamination, especially by emerging pollutants like pharmaceuticals and personal care products [4,5]. Many traditional water and wastewater treatment methods do not effectively remove these emerging contaminants, and/or are not capable of removing enough to meet increasingly stringent water quality standards [5,6]. Contamination of surface waters also constitutes a risk to water supplies because pollutants may penetrate into aquifers, where they can be transported to drinking water sources.
Engineered Nanomaterials for Water Treatment and Remediation
Water is one of the world’s most abundant resources, but less than 1% of the global supply of water is available and safe for human consumption [1]. According to the World Health Organization, over 760 million people were without adequate drinking water supply in 2011 [2]. Where it is available, the cost of potable water is rising due to increasing energy costs, growing populations, and climatic or other environmental issues [1,3]. In addition, an increasing number of drinking water sources are showing evidence of contamination, especially by emerging pollutants like pharmaceuticals and personal care products [4,5]. Many traditional water and wastewater treatment methods do not effectively remove these emerging contaminants, and/or are not capable of removing enough to meet increasingly stringent water quality standards [5,6]. Contamination of surface waters also constitutes a risk to water supplies because pollutants may penetrate into aquifers, where they can be transported to drinking water sources.
A Review of the Water Desalination Technologies
Abstract: Desalination is commonly adopted nowadays to overcome the freshwater scarcity in
some areas of the world if brackish water or salt water is available. Different kinds of technologies
have been proposed in the last century. In this paper, the state of the mainstream solutions is
reported, showing the current commercial technologies like reverse osmosis (RO), Multi-Stages Flash
desalination (MSF) and Multi-Effect Distillation (MED), and the new frontiers of the research with
the aim of exploiting renewable sources such as wind, solar and biomass energy. In these cases,
seawater treatment plants are the same as traditional ones, with the only difference being that they
use a renewable energy source. Thus, classifications are firstly introduced, considering the working
principles, the main energy input required for the treatment, and the potential for coupling with
renewable energy sources. Each technology is described in detail, showing how the process works
and reporting some data on the state of development. Finally, a statistical analysis is given concerning
the spread of the various technologies across the world and which of them are most exploited. In this
section, an important energy and exergy analysis is also addressed to quantify energy losses.
A Review of the Water Desalination Technologies
Abstract: Desalination is commonly adopted nowadays to overcome the freshwater scarcity in
some areas of the world if brackish water or salt water is available. Different kinds of technologies
have been proposed in the last century. In this paper, the state of the mainstream solutions is
reported, showing the current commercial technologies like reverse osmosis (RO), Multi-Stages Flash
desalination (MSF) and Multi-Effect Distillation (MED), and the new frontiers of the research with
the aim of exploiting renewable sources such as wind, solar and biomass energy. In these cases,
seawater treatment plants are the same as traditional ones, with the only difference being that they
use a renewable energy source. Thus, classifications are firstly introduced, considering the working
principles, the main energy input required for the treatment, and the potential for coupling with
renewable energy sources. Each technology is described in detail, showing how the process works
and reporting some data on the state of development. Finally, a statistical analysis is given concerning
the spread of the various technologies across the world and which of them are most exploited. In this
section, an important energy and exergy analysis is also addressed to quantify energy losses.
Removal Of Polar Organic Micropollutants By Pilot-Scale Reverse Osmosis Drinking Water Treatment
Abstract : The robustness of reverse osmosis (RO) against polar organic micropollutants (MPs) was investigated in
pilot-scale drinking water treatment. Experiments were carried in hypoxic conditions to treat a raw anaerobic riverbank filtrate spiked with a mixture of thirty model compounds. The chemicals were selected from scientific literature data based on their relevance for the quality of freshwater systems, RO permeate and drinking water. MPs passage and the influence of permeate flux were evaluated with a typical low-pressure RO membrane and quantified by liquid chromatography coupled to high-resolution mass spectrometry. A strong inverse correlation between size and passage of neutral hydrophilic compounds was observed. This correlation was weaker for moderately hydrophobic MPs. Anionic MPs displayed nearly no passage due to electrostatic repulsion with the negatively charged membrane surface,
whereas breakthrough of small cationic MPs could be observed. The passage figures observed for the investigated set of MPs ranged from less than 1%e25%. Statistical analysis was performed to evaluate the relationship between physicochemical properties and passage. The effects of permeate flux were more pronounced for small neutral MPs, which displayed a higher passage after a pressure drop.
Removal Of Polar Organic Micropollutants By Pilot-Scale Reverse Osmosis Drinking Water Treatment
Abstract : The robustness of reverse osmosis (RO) against polar organic micropollutants (MPs) was investigated in
pilot-scale drinking water treatment. Experiments were carried in hypoxic conditions to treat a raw anaerobic riverbank filtrate spiked with a mixture of thirty model compounds. The chemicals were selected from scientific literature data based on their relevance for the quality of freshwater systems, RO permeate and drinking water. MPs passage and the influence of permeate flux were evaluated with a typical low-pressure RO membrane and quantified by liquid chromatography coupled to high-resolution mass spectrometry. A strong inverse correlation between size and passage of neutral hydrophilic compounds was observed. This correlation was weaker for moderately hydrophobic MPs. Anionic MPs displayed nearly no passage due to electrostatic repulsion with the negatively charged membrane surface,
whereas breakthrough of small cationic MPs could be observed. The passage figures observed for the investigated set of MPs ranged from less than 1%e25%. Statistical analysis was performed to evaluate the relationship between physicochemical properties and passage. The effects of permeate flux were more pronounced for small neutral MPs, which displayed a higher passage after a pressure drop.
Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures
Biofouling is a critical issue in membrane water and wastewater treatment as it greatly compromises the efficiency of the treatment processes. It is difficult to control, and significant economic resources have been dedicated to the development of effective biofouling monitoring and control strategies. This paper highlights the underlying causes of membrane biofouling and provides a review on recent developments of potential monitoring and control methods in water and wastewater treatment with the aim of identifying the remaining issues and challenges in this area.
Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures
Biofouling is a critical issue in membrane water and wastewater treatment as it greatly compromises the efficiency of the treatment processes. It is difficult to control, and significant economic resources have been dedicated to the development of effective biofouling monitoring and control strategies. This paper highlights the underlying causes of membrane biofouling and provides a review on recent developments of potential monitoring and control methods in water and wastewater treatment with the aim of identifying the remaining issues and challenges in this area.
Correlating BOD5 and COD of Sewage in Wastewater Treatment Plants Case Study Al- Diwaniyah WWTP in Iraq
ABSTRACT
This study aims to establish an empirical correlation between biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) of the sewage flowing in Al-Diwaniyah wastewater treatment plant. The strength of the wastewater entering the plant varied from medium to high. High concentrations of BOD5 and COD in the effluent were obtained due to the poor performance of the plant. This was observed from the BOD5 /COD ratios that did not confirm with the typical ratios for the treated sewage. To improve the performance of this plant, regression equations for BOD5 and COD removal percentages were suggested which can be used to facilitate rapid effluent assessment or optimal process control. The equations relating the percentage removal of BOD5(y) with influent BOD5(x), y= 0.044x + 80.66 and the percentage removal of COD (y) with influent COD (x), y= 0.045x + 55.15 were found with high correlation R2 =0.72 and 0.86 respectively. Key words: Sewage treatment, BOD5, COD, BOD5/COD ratio, BOD5&COD correlations
Correlating BOD5 and COD of Sewage in Wastewater Treatment Plants Case Study Al- Diwaniyah WWTP in Iraq
ABSTRACT
This study aims to establish an empirical correlation between biochemical oxygen demand (BOD5) and chemical oxygen demand (COD) of the sewage flowing in Al-Diwaniyah wastewater treatment plant. The strength of the wastewater entering the plant varied from medium to high. High concentrations of BOD5 and COD in the effluent were obtained due to the poor performance of the plant. This was observed from the BOD5 /COD ratios that did not confirm with the typical ratios for the treated sewage. To improve the performance of this plant, regression equations for BOD5 and COD removal percentages were suggested which can be used to facilitate rapid effluent assessment or optimal process control. The equations relating the percentage removal of BOD5(y) with influent BOD5(x), y= 0.044x + 80.66 and the percentage removal of COD (y) with influent COD (x), y= 0.045x + 55.15 were found with high correlation R2 =0.72 and 0.86 respectively. Key words: Sewage treatment, BOD5, COD, BOD5/COD ratio, BOD5&COD correlations
Nanotechnology in Water Treatment
ABSTRACT Drinking water is unfortunately becoming a rare luxury on our planet.On the other hand, with a trend of population growth, need for water which is essential to life,is becomingbigger every day.Practical application of nanotechnology in saving water worldwide is in using nanoparticles in detection of water pollution and water purification. This knowledge has importance in medicine and public health, so as in environment safety.Possible application areas of nanotechnology in field of purification and treatment of water are in filtration, catalytic and separation processes, ion exchanging, sensitive pollutant detection,etc.Nanotechnology could be the main solution in future fortreatment of surface water,groundwater, and waste water contaminated by toxic metal ions, organic and inorganic solutes, and microorganisms.
Nanotechnology in Water Treatment
ABSTRACT Drinking water is unfortunately becoming a rare luxury on our planet.On the other hand, with a trend of population growth, need for water which is essential to life,is becomingbigger every day.Practical application of nanotechnology in saving water worldwide is in using nanoparticles in detection of water pollution and water purification. This knowledge has importance in medicine and public health, so as in environment safety.Possible application areas of nanotechnology in field of purification and treatment of water are in filtration, catalytic and separation processes, ion exchanging, sensitive pollutant detection,etc.Nanotechnology could be the main solution in future fortreatment of surface water,groundwater, and waste water contaminated by toxic metal ions, organic and inorganic solutes, and microorganisms.
Calibration And Verification Of The Hydraulic Model For Blue Nile River from Roseries Dam To Khartoum City
ABSTRACT:
This research represents a practical attempt applied to calibrate and verify a hydraulic model for the Blue Nile River. The calibration procedures are performed using the observed data for a previous period and comparing them with the calibration results while verification requirements are achieved with the application of the observed data for another future period and comparing them with the verification results. The study objective covered a relationship of the river terrain with the distance between the assumed points of the dam failures along the river length. The computed model values and the observed data should conform to the theoretical analysis and the overall verification performance of the model by comparing it with another set of data. The model was calibrated using data from gauging stations (Khartoum, Wad Medani, downstream Sennar, and downstream Roseires) during the period from the 1st of May to 31 of October 1988 and the verification was done using the data of the same gauging stations for years 2003 and 2010 for the same period. The required available data from these stations were collected, processed and used in the model calibration. The geometry input files for the HEC-RAS models were created using a combination of ArcGIS and HEC-GeoRAS. The results revealed high correlation (R2 ˃ 0.9) between the observed and calibrated water levels in all gauging stations during 1988 and also high correlation between the observed and verification water levels was obtained in years 2003 and 2010. Verification results with the equation and degree of correlation can be used to predict future data of any expected data for the same stations.
Calibration And Verification Of The Hydraulic Model For Blue Nile River from Roseries Dam To Khartoum City
ABSTRACT:
This research represents a practical attempt applied to calibrate and verify a hydraulic model for the Blue Nile River. The calibration procedures are performed using the observed data for a previous period and comparing them with the calibration results while verification requirements are achieved with the application of the observed data for another future period and comparing them with the verification results. The study objective covered a relationship of the river terrain with the distance between the assumed points of the dam failures along the river length. The computed model values and the observed data should conform to the theoretical analysis and the overall verification performance of the model by comparing it with another set of data. The model was calibrated using data from gauging stations (Khartoum, Wad Medani, downstream Sennar, and downstream Roseires) during the period from the 1st of May to 31 of October 1988 and the verification was done using the data of the same gauging stations for years 2003 and 2010 for the same period. The required available data from these stations were collected, processed and used in the model calibration. The geometry input files for the HEC-RAS models were created using a combination of ArcGIS and HEC-GeoRAS. The results revealed high correlation (R2 ˃ 0.9) between the observed and calibrated water levels in all gauging stations during 1988 and also high correlation between the observed and verification water levels was obtained in years 2003 and 2010. Verification results with the equation and degree of correlation can be used to predict future data of any expected data for the same stations.
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