Nanotechnology for Water Purification

Hybrid processes combining activated carbon and nanofiltration have been studied to identify the optimum solution for advanced wastewater treatment in high quality water reclamation and reuse. With a focus on the removal of bulk and trace organic compounds the investigation identified three promising process combinations, namely powdered activated carbon followed by nanofiltration (PAC/NF), granular activated carbon followed by nanofiltration (GAC/NF) and nanofiltration followed by granular activated carbon (NF/GAC). The removal potential was examined in lab and pilot scale for a range of refractory pharmaceuticals and industrial chemicals typically detected in effluent in trace concentrations ranging from ng/L to μg/L. Fluorescence excitation emission spectroscopy was employed for the investigation of the fate of effluent organic matter. The optimum strategies for operation of the hybrid processes were determined in pilot scale. The experiments were conducted at the Wastewater Treatment Plant Aachen Soers providing an effluent of high quality with low dissolved organic carbon (DOC) concentrations of about 5 mg/L.

Conventional wastewater treatment technologies improve the quality of wastewater discharged into the environment and restrain polluted waters from contaminating other available clean water resources. However, these treatment technologies do not make wastewater fit for further beneficial uses in communities closer to the points of generation. Innovative and advanced technologies that can further improve the quality of wastewater are needed to overcome this limitation of conventional technologies, and to promote widespread adoption of recycle and reuse practices. Advanced treatment processes can be biological processes, physicochemical processes, or a combination of both (hybrid processes). Biological processes to remove nutrient pollutants such as nitrogen and phosphorus, provide the platform for further wastewater treatment to reusable quality. Physicochemical processes such as deep-bed filtration, floating media filtration, and membrane filtration, play a major role among treatment technologies for water reuse. Membrane filtration has significant advantages over other processes since they produce high quality effluent that requires little or no disinfection with minimum sludge generation. The hybrid processes attempt to obtain the benefits of both biological and physicochemical processes in one step.

Introduction Every year in South Africa an estimated R500m is spent on chemicals used in the treatment of drinking and waste water. Most of this money is allocated on the basis of tenders issued and contracts awarded. The evaluation of tenders is generally undertaken by a team of people from various disciplines within the awarding organization and the decisions they make can have a significant effect on the quality of water or waste that is produced and also on the finances of the organization for which they work. It is obvious therefore that these decisions – which chemicals to use, how much to use, how much should be paid, who is the most professional supplier – are important ones and ones that should be taken whilst in possession of the most factual and impartial information. This guide aims to provide those decision-makers, and other users of water treatment chemicals, with specific and useful information about water treatment chemicals. It is a chemistry text book aimed specifically at those people who have to make informed decisions but who have not had a formal education in chemistry or whose chemistry education has not been specific in detail relevant to water treatment chemicals. It does not, however, aim to be a comprehensive chemistry textbook and chemicals not used in water treatment are not discussed; nor are properties that are irrelevant to the water treatment application of the chemical. The guide is designed to serve as a reference book with each chapter being self contained and specific. It will be easily understood by those readers that do not have a formal chemistry education and hopefully will provide some useful additional insight and information to those that The guide is divided into ten chapters and includes an appendix at the end that contains various useful equations. The contents of each chapter are listed below.

Over the last few decades adsorption has gained paramount importance in industry and environmental protection. Adsorption processes are widely applied for separation and purification because of the high reliability, energy efficiency, design flexibility, technological maturity and the ability to regenerate the exhausted adsorbent. One method of important extending the adsorption treatment processes is biofiltration. The biological filter relies on the activities of the community of micro-organisms that become attached onto the filter media. Microbes oxidize organic matters in water to produce energy and therefore available nutrients sources in feed water are essential for their development. Biofiltration can effectively remove organic matter that is not able to be removed from water and biologically treated sewage effluent in conventional sewage treatment. The microbial attachment process, the factors that influence biological filtration, the kinetics of microbial growth and details of the microbial community in the biofilter are discussed in detail. There are several types of biofilters including submerged filters, trickling filter, bed filter, fluidised bed. The different biofilters are described and a comparison between them is provided. The application of biofilters for treating various types of wastewater effluent is detailed.

•List the key monitoring points within the activated sludge process and explain what to look for at those points. •List five key process control parameters and for each parameter, explain what it is, why it is used and how it is calculated •List the daily process control tasks that need to be accomplished and explain how to perform them.