Water Desalination & RO
Boron Rejection by Reverse Osmosis Membranes – National Reconnaissance and Mechanism Study
Boron Rejection by Reverse Osmosis Membranes – National Reconnaissance and Mechanism Study
Source: https://www.usbr.gov/
Author by: Mark Wilf, Jong-Sang Park and Jess Brown
Introduction
The mechanism of boron rejection by reverse osmosis membrane and transport was studied by bench experiments using six commercial reverse osmosis membranes.
A mathematical model was developed to predict boron rejection by reverse osmosis membranes under different operating conditions such as pressure, pH, and temperature.
Boron concentrations in feed and product water from nine pilot or full-scale plants were analyzed in parallel.
Comparison with bench-scale data suggested that the level is much lower than the boron rejection observed in the field data, mainly due to the high target recovery rate.
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Related books
A Primer On Brackish And Seawater Desalination
Abstract: This publication was produced as an activity of the Texas Living Waters Project. This project
is a collaborative effort of the National Wildlife Federation, Environmental Defense, and the Lone
Star Chapter of the Sierra Club. The goals of the project are to 1) ensure adequate water for people
and environmental needs, 2) reduce future demand for water and foster efficient and sustainable use
of current water supplies, 3) educate the public and decision makers about the impact of wasteful
water use and the opportunities for water conservation, and 4) involve citizens in the decision
making process for water management.
A Primer On Brackish And Seawater Desalination
Abstract: This publication was produced as an activity of the Texas Living Waters Project. This project
is a collaborative effort of the National Wildlife Federation, Environmental Defense, and the Lone
Star Chapter of the Sierra Club. The goals of the project are to 1) ensure adequate water for people
and environmental needs, 2) reduce future demand for water and foster efficient and sustainable use
of current water supplies, 3) educate the public and decision makers about the impact of wasteful
water use and the opportunities for water conservation, and 4) involve citizens in the decision
making process for water management.
Basics of Reverse Osmosis
What is Reverse Osmosis?
Reverse Osmosis is a technology that is used to remove a large majority of contaminants from water by
pushing the water under pressure through a semi permeable membrane. This paper is aimed towards an audience that has little of no experience with Reverse Osmosis and will attempt to explain the basics
in simple terms that should leave the reader with a better overall understanding of Reverse Osmosis technology and its applications.
Basics of Reverse Osmosis
What is Reverse Osmosis?
Reverse Osmosis is a technology that is used to remove a large majority of contaminants from water by
pushing the water under pressure through a semi permeable membrane. This paper is aimed towards an audience that has little of no experience with Reverse Osmosis and will attempt to explain the basics
in simple terms that should leave the reader with a better overall understanding of Reverse Osmosis technology and its applications.
Desalination Plant Basis Of Design
Overview:
The project potable water requirements will be provided using single desalination plant with the Grand Bahama Port Authority water supply serving as the backup source. The overall desalination treatment process will consist of feedwater pumping, bag filtration, optional media filtration, the addition of a scale
inhibitor, cartridge filtration, membrane separation, forced air degasification, re-pumping, and post treatment. Provisions have been included to bypass the post treatment systems for the production of irrigation water. The post aeration re-pump station will be designed to transfer either type of water to the
appropriate storage tanks located within the project. Membrane concentrate will be disposed via an injection well to be constructed as part of this project.
The desalination process will consist of a dual treatment units or “trains” each equipped with a positive displacement axial piston first pass membrane feed pump, first pass membrane array, energy recovery system, second pass membrane feed pump, second pass membrane array, high- and low-pressure
piping and instrumentation. The second pass system is designed to treat up to 60 percent of the first pass permeate. A membrane cleaning/flush system will be provided. The membrane post treatment will be designed to receive the flow from both units and consists of a forced air degasified, repumping, recarbonation, calcium carbonate up flow contactors to boost finished water hardness and alkalinity concentrations; and three chemical feed systems for the metering of a corrosion inhibitor, dilute hydrochloric acid for pH adjustment and sodium hypochlorite for residual disinfection. The final pH and chlorine residual will be controlled and recorded by a separate system. The following sections describe the various aspects of the facility in greater detail. Process flow
schematics are presented in Appendix A.
Desalination Plant Basis Of Design
Overview:
The project potable water requirements will be provided using single desalination plant with the Grand Bahama Port Authority water supply serving as the backup source. The overall desalination treatment process will consist of feedwater pumping, bag filtration, optional media filtration, the addition of a scale
inhibitor, cartridge filtration, membrane separation, forced air degasification, re-pumping, and post treatment. Provisions have been included to bypass the post treatment systems for the production of irrigation water. The post aeration re-pump station will be designed to transfer either type of water to the
appropriate storage tanks located within the project. Membrane concentrate will be disposed via an injection well to be constructed as part of this project.
The desalination process will consist of a dual treatment units or “trains” each equipped with a positive displacement axial piston first pass membrane feed pump, first pass membrane array, energy recovery system, second pass membrane feed pump, second pass membrane array, high- and low-pressure
piping and instrumentation. The second pass system is designed to treat up to 60 percent of the first pass permeate. A membrane cleaning/flush system will be provided. The membrane post treatment will be designed to receive the flow from both units and consists of a forced air degasified, repumping, recarbonation, calcium carbonate up flow contactors to boost finished water hardness and alkalinity concentrations; and three chemical feed systems for the metering of a corrosion inhibitor, dilute hydrochloric acid for pH adjustment and sodium hypochlorite for residual disinfection. The final pH and chlorine residual will be controlled and recorded by a separate system. The following sections describe the various aspects of the facility in greater detail. Process flow
schematics are presented in Appendix A.
Cleaning Your RO
Eventually the day comes when your RO system will require cleaning. Cleaning is recommended when your RO shows evidence of fouling, just prior to a long term shutdown, or as a matter of scheduled routine maintenance. Fouling characteristics that signal you need to clean are a 10-15% decrease in normalized permeate flow, a 10-15% decrease in normalized permeate quality, or a 10-15% increase in normalized pressure drop as measured between the feed and concentrate headers
Cleaning Your RO
Eventually the day comes when your RO system will require cleaning. Cleaning is recommended when your RO shows evidence of fouling, just prior to a long term shutdown, or as a matter of scheduled routine maintenance. Fouling characteristics that signal you need to clean are a 10-15% decrease in normalized permeate flow, a 10-15% decrease in normalized permeate quality, or a 10-15% increase in normalized pressure drop as measured between the feed and concentrate headers
Database Of Permitting Practices For Seawater Desalination Concentrate
Abstract:
The purpose of this research project was to identify the discharge information that permitting agencies need and the decision-making process they go through to permit discharge methods in order to help desalination project proponents focus and expedite their permitting efforts.
The project documented seawater reverse osmosis (SWRO) discharge regulatory issues and provided a critical overview of facility discharge-related information required for permitting desalination projects in the United States and selected countries with advanced environmental regulations and experience in implementing seawater desalination projects. Information was gathered from the three key U.S. states (California, Florida, Texas) where interest in SWRO desalination has been highest. Due to the more extensive international experience with SWRO desalination, information was also obtained from the countries of Australia, Israel, and Spain – all countries of significant recent large-scale SWRO desalination projects. Case studies of 11 SWRO plants and analysis of regulatory systems and permitting processes supported detailed definition of the decision-making process to set discharge permit limits, as well as defining environmental and other regulatory issues associated with concentrate regulation.
Database Of Permitting Practices For Seawater Desalination Concentrate
Abstract:
The purpose of this research project was to identify the discharge information that permitting agencies need and the decision-making process they go through to permit discharge methods in order to help desalination project proponents focus and expedite their permitting efforts.
The project documented seawater reverse osmosis (SWRO) discharge regulatory issues and provided a critical overview of facility discharge-related information required for permitting desalination projects in the United States and selected countries with advanced environmental regulations and experience in implementing seawater desalination projects. Information was gathered from the three key U.S. states (California, Florida, Texas) where interest in SWRO desalination has been highest. Due to the more extensive international experience with SWRO desalination, information was also obtained from the countries of Australia, Israel, and Spain – all countries of significant recent large-scale SWRO desalination projects. Case studies of 11 SWRO plants and analysis of regulatory systems and permitting processes supported detailed definition of the decision-making process to set discharge permit limits, as well as defining environmental and other regulatory issues associated with concentrate regulation.
Tailoring Advanced Desalination Technologies for 21st Century Agriculture
Abstract: Substantial parts of the U.S., particularly drier landlocked regions, are facing acute water shortages and water quality issues that decrease agricultural productivity. Reduced crop yields cause billions of dollars in losses annually, affecting the livelihoods of thousands. A combination of population growth, inefficient agricultural practices, and resource demanding consumption trends is only expected to increase pressure on our water supplies. This research proposal seeks to address water and food security issues by cost-effectively and energy-efficiently enhancing water quality and water supply in greenhouses; a $22.93 billion dollar industry in 2017 that is rapidly growing at an annual rate of 8.92%. Greenhouses widely practice desalination of salty irrigation water to improve their operations. However, currently used desalination methods do not tailor greenhouse waters based on crop requirements. This work investigates a fully integrated desalination solution that treats and tailors brackish source waters ingreenhouses to save fertilizer and water. Specifically, this project experimentally studies multi-ion transport in and assesses the economic viable of monovalent selective electrodialysis (MSED). MSED allows for the selective removal of monovalent ions damaging to crops and the retention of divalent ions beneficial for crops, unlike the widely used reverse osmosis (RO), which removes all ions from greenhouse source water. First, we evaluate the techno-economic feasibility of MSED compared to other brackish desalination technologies for agricultural applications, based on primary market research we conduct with over 70 greenhouses.
These include conventional technologies, such as reverse osmosis (RO) and electrodialysis (ED), and advanced technologies, such as closed circuit reverse osmosis (CCRO). The analysis determines the levelized costs of water, the capital costs and energy requirements of these technologies, and how these vary with feed salinity, system capacity and recovery ratio. Then, we build a bench-scale setup to experientially characterize MSED membrane properties, including monovalent selectivity, ion transport, limiting current and resistance, for multiple brackish feedwaters and for two sets of MSED membranes: the widely used Neosepta ACS/CMS membranes and the new Fujifilm Type 16 membranes. Both MSED membranes show notable monovalent selectivity for all tested compositions, reflecting the potential of the technology for selective desalination in greenhouses. The measurements are compared to a model for MSED in multi-ion solutions. The model predicts multi-ion transport for the Neosepta and Fujifilm MSED systems within 6% and 8%, respectively.
Tailoring Advanced Desalination Technologies for 21st Century Agriculture
Abstract: Substantial parts of the U.S., particularly drier landlocked regions, are facing acute water shortages and water quality issues that decrease agricultural productivity. Reduced crop yields cause billions of dollars in losses annually, affecting the livelihoods of thousands. A combination of population growth, inefficient agricultural practices, and resource demanding consumption trends is only expected to increase pressure on our water supplies. This research proposal seeks to address water and food security issues by cost-effectively and energy-efficiently enhancing water quality and water supply in greenhouses; a $22.93 billion dollar industry in 2017 that is rapidly growing at an annual rate of 8.92%. Greenhouses widely practice desalination of salty irrigation water to improve their operations. However, currently used desalination methods do not tailor greenhouse waters based on crop requirements. This work investigates a fully integrated desalination solution that treats and tailors brackish source waters ingreenhouses to save fertilizer and water. Specifically, this project experimentally studies multi-ion transport in and assesses the economic viable of monovalent selective electrodialysis (MSED). MSED allows for the selective removal of monovalent ions damaging to crops and the retention of divalent ions beneficial for crops, unlike the widely used reverse osmosis (RO), which removes all ions from greenhouse source water. First, we evaluate the techno-economic feasibility of MSED compared to other brackish desalination technologies for agricultural applications, based on primary market research we conduct with over 70 greenhouses.
These include conventional technologies, such as reverse osmosis (RO) and electrodialysis (ED), and advanced technologies, such as closed circuit reverse osmosis (CCRO). The analysis determines the levelized costs of water, the capital costs and energy requirements of these technologies, and how these vary with feed salinity, system capacity and recovery ratio. Then, we build a bench-scale setup to experientially characterize MSED membrane properties, including monovalent selectivity, ion transport, limiting current and resistance, for multiple brackish feedwaters and for two sets of MSED membranes: the widely used Neosepta ACS/CMS membranes and the new Fujifilm Type 16 membranes. Both MSED membranes show notable monovalent selectivity for all tested compositions, reflecting the potential of the technology for selective desalination in greenhouses. The measurements are compared to a model for MSED in multi-ion solutions. The model predicts multi-ion transport for the Neosepta and Fujifilm MSED systems within 6% and 8%, respectively.
Desalination and Membrane Technologies: Federal Research and Adoption Issues
In the United States, desalination and membrane technologies are used to augment municipal water supply, produce high-quality industrial water supplies, and reclaim contaminated supplies (including from oil and gas development). Approximately 2,000 desalination facilities larger than
0.3 million gallons per day (MGD) operate in the United States; this represents more than 2% of U.S. municipal and industrial freshwater use. At issue for Congress is what should be the federal role in supporting desalination and membrane technology research and facilities. Desalination issues before the 114th Congress may include how to focus federal research, at what level to support desalination research and projects, and how to provide a regulatory context that protects the environment and public health without disadvantaging desalination’s adoption.
Desalination and Membrane Technologies: Federal Research and Adoption Issues
In the United States, desalination and membrane technologies are used to augment municipal water supply, produce high-quality industrial water supplies, and reclaim contaminated supplies (including from oil and gas development). Approximately 2,000 desalination facilities larger than
0.3 million gallons per day (MGD) operate in the United States; this represents more than 2% of U.S. municipal and industrial freshwater use. At issue for Congress is what should be the federal role in supporting desalination and membrane technology research and facilities. Desalination issues before the 114th Congress may include how to focus federal research, at what level to support desalination research and projects, and how to provide a regulatory context that protects the environment and public health without disadvantaging desalination’s adoption.
Desalination In Water Treatment And Sustainability
ABSTRACT:
The purpose of this Bachelor’s thesis was to introduce different desalination technologies in solving water scarcity in countries where access to safe drinking water is limited, due to increasing population growth, industrial activities and agriculture. This thesis covers and explains different desalination technologies in dealing with water problems in different countries and the best suitable methods. The thesis was commissioned by HAMK University of Applied Sciences.
The thesis also focuses on the Economic and Social Commission for West Asia (ESCWA) member countries were access to water is limited due to scanty rainfall and dry lands. Desalination technology has played a significant role in solving their water scarcity in the region leading to sustainable development. A case study of Taweelah power and desalination plant in Abu Dhabi was explained providing detailed information. As a conclusion, it can be stated that desalination in water treatment and sustainability is a significant factor in the world today, because the future of water supply requires adequate sustainability to be able to effectively supply and support the world’s increasing population. For the Taweelah power and desalination plant project, a suitable re-design of the intakes and outfall layout should be adjusted. The outfall can be an offshore pipeline instead of its location onshore.
Desalination In Water Treatment And Sustainability
ABSTRACT:
The purpose of this Bachelor’s thesis was to introduce different desalination technologies in solving water scarcity in countries where access to safe drinking water is limited, due to increasing population growth, industrial activities and agriculture. This thesis covers and explains different desalination technologies in dealing with water problems in different countries and the best suitable methods. The thesis was commissioned by HAMK University of Applied Sciences.
The thesis also focuses on the Economic and Social Commission for West Asia (ESCWA) member countries were access to water is limited due to scanty rainfall and dry lands. Desalination technology has played a significant role in solving their water scarcity in the region leading to sustainable development. A case study of Taweelah power and desalination plant in Abu Dhabi was explained providing detailed information. As a conclusion, it can be stated that desalination in water treatment and sustainability is a significant factor in the world today, because the future of water supply requires adequate sustainability to be able to effectively supply and support the world’s increasing population. For the Taweelah power and desalination plant project, a suitable re-design of the intakes and outfall layout should be adjusted. The outfall can be an offshore pipeline instead of its location onshore.
Desalination: A National Perspective
NOTICE:
The project that is the subject of this report was approved by the Governing Board of the National Research Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of Engineering, and the Institute of Medicine. The members of the panel responsible for the report were chosen for their special competences and with regard for appropriate balance.
Support for this study was provided by the U.S. Bureau of Reclamation under Grant No. 06CS811198. Any opinions, findings, conclusions, or recommendations expressed in this publication are those of the author(s) and do not necessarily reflect the views of the organizations or agencies that provided
support for the project.
Desalination: A National Perspective
NOTICE:
The project that is the subject of this report was approved by the Governing Board of the National Research Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of Engineering, and the Institute of Medicine. The members of the panel responsible for the report were chosen for their special competences and with regard for appropriate balance.
Support for this study was provided by the U.S. Bureau of Reclamation under Grant No. 06CS811198. Any opinions, findings, conclusions, or recommendations expressed in this publication are those of the author(s) and do not necessarily reflect the views of the organizations or agencies that provided
support for the project.
Desalination For Safe Water Supply
Preface:
Access to sufficient quantities of safe water for drinking and domestic uses and also for commercial and industrial applications is critical to health and well being, and the opportunity to achieve human and economic development. People in many areas of the world have historically suffered from inadequate access to safe water. Some must walk long distances just to obtain sufficient water to sustain life. As a result they have had to endure health consequences and have not had the opportunity to develop their resources and capabilities to achieve major improvements in their well being. With growth of world population the availability of the limited quantities of fresh water decreases. Desalination technologies were introduced about 50 years ago at and were able to expand access to water, but at high cost. Developments of new and improved technologies have now significantly broadened the opportunities to access major quantities of safe water in many parts of the world. Costs are still significant but there has been a reducing cost trend, and the option is much more widely available. When the alternative is no water or inadequate water greater cost may be endurable in many circumstances.
Desalination For Safe Water Supply
Preface:
Access to sufficient quantities of safe water for drinking and domestic uses and also for commercial and industrial applications is critical to health and well being, and the opportunity to achieve human and economic development. People in many areas of the world have historically suffered from inadequate access to safe water. Some must walk long distances just to obtain sufficient water to sustain life. As a result they have had to endure health consequences and have not had the opportunity to develop their resources and capabilities to achieve major improvements in their well being. With growth of world population the availability of the limited quantities of fresh water decreases. Desalination technologies were introduced about 50 years ago at and were able to expand access to water, but at high cost. Developments of new and improved technologies have now significantly broadened the opportunities to access major quantities of safe water in many parts of the world. Costs are still significant but there has been a reducing cost trend, and the option is much more widely available. When the alternative is no water or inadequate water greater cost may be endurable in many circumstances.
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