Cross Flow Filtration Method Handbook

Surging population, energy demands, and climate change will push us, ever more urgently, to find new approaches to meet growing water demands. Most often, this will involve harvesting lower quality or impaired water supplies (e.g., seawater or brackish groundwater) as a source for drinking water. Recently desalination using membrane-based processes (e.g., reverse osmosis [RO], electrodialysis [ED], and nanofiltration [NF]) has shown promise for providing additional sources of fresh water across the United States. However, the current membrane separation processes are commonly energy intensive and produce large volumes of concentrated brine which poses unique challenges. Particularly in land-locked urban center brine disposal often relyes on surface water discharge or deep-well injection which pose economic and practical difficulties for wide-spread adoption of such technologies. Thus, there is an urgent need for energy-efficient desalination technologies that reduce the amount of concentrate produced, or identify cost-effective solutions for concentrate management.

This paper aims at analyzing the drinking water issue in the Mediterranean region, highlighting the principal problems and the appropriate technologies applicable in the different countries. The countries of this area are characterized by a huge variety from social, cultural, economic and environmental point of view. In particular, water distribution is inhomogeneous between the North, East, and South; even the type of water sources and the related quantity and quality problems differ country by country. Potable water comes from brackish and seawater, surface water, groundwater and water reservoirs with each source face different issues. The main problem of brackish and seawater for example is the high salinity and the contamination by disinfection byproducts, in addition to the microbiological and chemical contamination due to human activities that characterize also other surface water sources. Groundwater is also affected by human activity and it is not exempted from salinity because of the water intrusion. Moreover, water reservoirs are often contaminated by seasonal algal blooms. Technologies applied for drinking water treatment vary country by country. The paper presents the main treatment processes associated with the main water pollutants, according to the Mediterranean region. Case studies of drinking water treatment plants are also analyzed, presenting alternative technologies appropriate for specific contexts, among others. The characteristics of each specific context should be carefully analyzed in order to develop the most appropriate technologies; high-end technologies for drinking water treatment may not be applied equally to all countries or communities of the Mediterranean region.

The 2006 version of the Pa. DEP Inorganic Contaminant Removal module has detailed advanced treatment information on this topic and can be obtained by e-mailing the Pa. DEP Safe Drinking Water Training Section at DEPWSTechtrain@pa.gov to request a copy. This advanced module has additional information on the removal of various inorganic contaminants as well as on oxidation, ion exchange, activated alumina and sequestration. The 2006 document also includes more detailed information on the inorganic contaminant treatments of GAC (granular activated carbon), coagulation/filtration, membranes, and lime softening. It includes the following information:

• Inorganic contaminant treatment selection considerations
• Advanced inorganic contaminant removal chemistry terminology
• Advanced inorganic contaminant removal chemistry explanations
• Conventional filtration and how it relates to inorganic removal
• Detailed information on treatments for iron and manganese removal
• Detailed information on treatments for hardness removal
• Detailed information on inorganic contaminant monitoring protocols
• Detailed tables on the following topics:
• Sources of 26 inorganic contaminants
• Common secondary standards with effects, inorganic contributors and indications
• Various treatment technology options to consider for 24 inorganic contaminants
• Potential forms of iron and manganese
• Iron and manganese sampling procedures
• Iron and manganese oxidant selection criteria
• Iron and manganese theoretical (initial) dosing criteria
• Potential treatments for less common inorganics
• Potential treatments for miscellaneous trace metals

In efforts to make package plants more compact, affordable and easier to operate and maintain, it has been noted that the design and performance of some of these plants containing conventional treatment processes is sometimes compromised if technical expertise in this regard is lacking. Generally, there are several risks associated with poorly designed treatment systems, including loss of production, poor safety and compromised equipment and process unit efficiency with associated higher operating and maintenance costs. These risks have more severe consequences in the case of desalination (including water reclamation and water re-use) package plants. The objective of this project is to develop a set of guidelines to assist municipalities, water treatment practitioners, designers and package plant manufacturers in the specification and design of appropriate unit processes and operating parameters to fit the influent water quality, operating environment and other special treatment requirements.

Introduction: Desalination using seawater reverse osmosis (SWRO) technology is an important option available to water-scarce coastal regions. Worldwide sea water desalination is a very effective and economical way of producing potable water for drinking and industries. Reverse osmosis plants to convert sea water to potable drinking water and for other usages have been prevalent throughout the world for more than 4 decades. Design and operation of seawater reverse osmosis plants strongly depend on the raw seawater quality to be treated. The performance of desalination reverse osmosis (RO) systems relies upon the production of high quality pre treated water, and the selection of the best pre treatment technology depends on the raw seawater quality and its variations. Number of full-scale experiences has shown that pre treatment is the key for this application of reverse osmosis technology. It is why during these last years, an import effort has been done to identify and to characterise the diverse organic and mineral components present in the seawater in a view to optimise the seawater pre-treatment and to develop advanced analytical methods for feed water characterization, appropriate fouling indicators and prediction tools. This Chapter describes firstly a comprehensive approach to characterize raw seawater samples through analytical tools which allow the knowledge of the characterization of seawater from many aspects: (a) inorganic content, (b) natural organic matter, (c) enumeration of micro-organisms and phytoplankton. Secondly, this Chapter describes the effect of each of these parameters on the fouling of the reverse osmosis membrane. Finally, this chapter describes the different possible pre treatments available to reduce or remove the elements or substances up-stream reverse osmosis stage.