Water Desalination & RO
Desalination, Trends and Technologies
Preface:
The sustainability and prosperity of the ancient civilizations of China, Egypt, Babylonia, Phoenicia, Persia and Roma were based on the extensive use of water for human consumption, crop irrigation, canal navigation and energy generation. Today, the worldwide scarcity of water and clean energy constitutes a central and critical problem for the whole humankind. This situation is aggravated as industrial, agricultural and municipal effluents reach the water bodies, or the coastal seawater that is used as feed for desalination plants. All these problems are linked to the actual, natural and anthropogenic changes of climate, global warming and greenhouse-gas emissions, all interrelated phenomena that affect our planet. In order to avoid damage to its facilities and equipment, the desalination industry invests considerable efforts to deal with these changes, in particular with extreme events such as torrential rains, devastating FL floods, dry seasons with devouring fifers, as well as with extended spells of cold weather with freezing temperatures. The book chapters are arranged in an hierarchical sequence, starting with conventional and novel desalination processes and following with energy, environmental, economic and ecological issues, all affecting the desalination industry image and profitability. Leading experts from academia and industry, as well as environment researchers, distinguished teachers and experienced engineers have writ en special chapters for this impressive collection. The contributing authors offer a large amount of practical information, presenting it in a highly condensed yet coherent body of useful knowledge and practical expertise. Moreover, the multi-authored characteristic of this volume offers a wide spectrum of knowledge and experience, as the authors are specialists in different fields and express diverse approaches and orientations. The intended multifacet content of this publication certainly contributes to enrich it. This compendium provides valuable, encyclopedic knowledge on research, development, processes, plants and technologies of this industry, from the fundamental concepts up to many practical cases collected from around the world. Hence, it provides a useful insight into the world of water, energy and desalination, easy to follow and to apply. This volume is an essential companion to chemists, as well as to civil and chemical engineers who design, build and operate desalination plants. It is also highly relevant to maintenance personnel, corrosion specialists, material- and mechanical engineers.
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Cleaning Your RO
Eventually the day comes when your RO system will require cleaning. Cleaning is recommended when your RO shows evidence of fouling, just prior to a long term shutdown, or as a matter of scheduled routine maintenance. Fouling characteristics that signal you need to clean are a 10-15% decrease in normalized permeate flow, a 10-15% decrease in normalized permeate quality, or a 10-15% increase in normalized pressure drop as measured between the feed and concentrate headers
Cleaning Your RO
Eventually the day comes when your RO system will require cleaning. Cleaning is recommended when your RO shows evidence of fouling, just prior to a long term shutdown, or as a matter of scheduled routine maintenance. Fouling characteristics that signal you need to clean are a 10-15% decrease in normalized permeate flow, a 10-15% decrease in normalized permeate quality, or a 10-15% increase in normalized pressure drop as measured between the feed and concentrate headers
Basics of Reverse Osmosis
What is Reverse Osmosis?
Reverse Osmosis is a technology that is used to remove a large majority of contaminants from water by
pushing the water under pressure through a semi permeable membrane. This paper is aimed towards an audience that has little of no experience with Reverse Osmosis and will attempt to explain the basics
in simple terms that should leave the reader with a better overall understanding of Reverse Osmosis technology and its applications.
Basics of Reverse Osmosis
What is Reverse Osmosis?
Reverse Osmosis is a technology that is used to remove a large majority of contaminants from water by
pushing the water under pressure through a semi permeable membrane. This paper is aimed towards an audience that has little of no experience with Reverse Osmosis and will attempt to explain the basics
in simple terms that should leave the reader with a better overall understanding of Reverse Osmosis technology and its applications.
Cleaning Procedures for Composite Polyamide RO Membrane Elements
Note: The Composite Polyamide type of RO membrane elements may not be
exposed to chlorinated water under any circumstances. Any such exposure may
cause irreparable damage to the membrane. Absolute care must be taken
following any disinfection of piping or equipment or the preparation of cleaning or
storage solutions to ensure that no trace of chlorine is present in the feedwater to
the RO membrane elements. If there is any doubt about the presence of chlorine,
perform chemical testing. Neutralize any chlorine residual with a sodium bisulfite
solution, and ensure adequate mixing and contact time to accomplish complete
dechlorination. Dosing rate is 1.8 to 3.0 ppm sodium bisulfite per 1.0 ppm of free
chlorine
Cleaning Procedures for Composite Polyamide RO Membrane Elements
Note: The Composite Polyamide type of RO membrane elements may not be
exposed to chlorinated water under any circumstances. Any such exposure may
cause irreparable damage to the membrane. Absolute care must be taken
following any disinfection of piping or equipment or the preparation of cleaning or
storage solutions to ensure that no trace of chlorine is present in the feedwater to
the RO membrane elements. If there is any doubt about the presence of chlorine,
perform chemical testing. Neutralize any chlorine residual with a sodium bisulfite
solution, and ensure adequate mixing and contact time to accomplish complete
dechlorination. Dosing rate is 1.8 to 3.0 ppm sodium bisulfite per 1.0 ppm of free
chlorine
Tailoring Advanced Desalination Technologies for 21st Century Agriculture
Abstract: Substantial parts of the U.S., particularly drier landlocked regions, are facing acute water shortages and water quality issues that decrease agricultural productivity. Reduced crop yields cause billions of dollars in losses annually, affecting the livelihoods of thousands. A combination of population growth, inefficient agricultural practices, and resource demanding consumption trends is only expected to increase pressure on our water supplies. This research proposal seeks to address water and food security issues by cost-effectively and energy-efficiently enhancing water quality and water supply in greenhouses; a $22.93 billion dollar industry in 2017 that is rapidly growing at an annual rate of 8.92%. Greenhouses widely practice desalination of salty irrigation water to improve their operations. However, currently used desalination methods do not tailor greenhouse waters based on crop requirements. This work investigates a fully integrated desalination solution that treats and tailors brackish source waters ingreenhouses to save fertilizer and water. Specifically, this project experimentally studies multi-ion transport in and assesses the economic viable of monovalent selective electrodialysis (MSED). MSED allows for the selective removal of monovalent ions damaging to crops and the retention of divalent ions beneficial for crops, unlike the widely used reverse osmosis (RO), which removes all ions from greenhouse source water. First, we evaluate the techno-economic feasibility of MSED compared to other brackish desalination technologies for agricultural applications, based on primary market research we conduct with over 70 greenhouses.
These include conventional technologies, such as reverse osmosis (RO) and electrodialysis (ED), and advanced technologies, such as closed circuit reverse osmosis (CCRO). The analysis determines the levelized costs of water, the capital costs and energy requirements of these technologies, and how these vary with feed salinity, system capacity and recovery ratio. Then, we build a bench-scale setup to experientially characterize MSED membrane properties, including monovalent selectivity, ion transport, limiting current and resistance, for multiple brackish feedwaters and for two sets of MSED membranes: the widely used Neosepta ACS/CMS membranes and the new Fujifilm Type 16 membranes. Both MSED membranes show notable monovalent selectivity for all tested compositions, reflecting the potential of the technology for selective desalination in greenhouses. The measurements are compared to a model for MSED in multi-ion solutions. The model predicts multi-ion transport for the Neosepta and Fujifilm MSED systems within 6% and 8%, respectively.
Tailoring Advanced Desalination Technologies for 21st Century Agriculture
Abstract: Substantial parts of the U.S., particularly drier landlocked regions, are facing acute water shortages and water quality issues that decrease agricultural productivity. Reduced crop yields cause billions of dollars in losses annually, affecting the livelihoods of thousands. A combination of population growth, inefficient agricultural practices, and resource demanding consumption trends is only expected to increase pressure on our water supplies. This research proposal seeks to address water and food security issues by cost-effectively and energy-efficiently enhancing water quality and water supply in greenhouses; a $22.93 billion dollar industry in 2017 that is rapidly growing at an annual rate of 8.92%. Greenhouses widely practice desalination of salty irrigation water to improve their operations. However, currently used desalination methods do not tailor greenhouse waters based on crop requirements. This work investigates a fully integrated desalination solution that treats and tailors brackish source waters ingreenhouses to save fertilizer and water. Specifically, this project experimentally studies multi-ion transport in and assesses the economic viable of monovalent selective electrodialysis (MSED). MSED allows for the selective removal of monovalent ions damaging to crops and the retention of divalent ions beneficial for crops, unlike the widely used reverse osmosis (RO), which removes all ions from greenhouse source water. First, we evaluate the techno-economic feasibility of MSED compared to other brackish desalination technologies for agricultural applications, based on primary market research we conduct with over 70 greenhouses.
These include conventional technologies, such as reverse osmosis (RO) and electrodialysis (ED), and advanced technologies, such as closed circuit reverse osmosis (CCRO). The analysis determines the levelized costs of water, the capital costs and energy requirements of these technologies, and how these vary with feed salinity, system capacity and recovery ratio. Then, we build a bench-scale setup to experientially characterize MSED membrane properties, including monovalent selectivity, ion transport, limiting current and resistance, for multiple brackish feedwaters and for two sets of MSED membranes: the widely used Neosepta ACS/CMS membranes and the new Fujifilm Type 16 membranes. Both MSED membranes show notable monovalent selectivity for all tested compositions, reflecting the potential of the technology for selective desalination in greenhouses. The measurements are compared to a model for MSED in multi-ion solutions. The model predicts multi-ion transport for the Neosepta and Fujifilm MSED systems within 6% and 8%, respectively.
Desalination & Water Purification Technologies
Introduction:
The world’s water consumption rate is doubling every 20 years, outpacing by two times the rate of population growth. The availability of good quality water is on the decline and water demand is on the rise. Worldwide availability of fresh water for industrial needs and human consumption is limited.
Various industrial and developmental activities in recent times have resulted in increasing the pollution level and deteriorating the water quality. Water shortages and unreliable water quality are considered major obstacles to achieve sustainable development and improvement in the quality of life. The water
demand in the country is increasing fast due to progressive increase in the demand of water for irrigation, rapid industrialization, and population growth and improving life standards. The existing water resources are diminishing (i) due to unequal distribution of rain water and occasional drought, (ii) excessive exploitation of ground water sources and its insufficient recharge, (iii) deterioration of water quality due to the discharge of domestic and industrial effluents without adequate treatment. This is resulting into water stress/ scarcity. Country is currently passing through social and economic transition.
The proportion of the population which is urban has doubled over the last thirty years (and is now about 30%), agriculture now accounts for about 25% of GDP and the economy has been growing at around 7-9% a year. Country has a highly seasonal pattern of rainfall, with 50% of precipitation falling
in just 15 days and over 90% of river flows in just four months
Desalination & Water Purification Technologies
Introduction:
The world’s water consumption rate is doubling every 20 years, outpacing by two times the rate of population growth. The availability of good quality water is on the decline and water demand is on the rise. Worldwide availability of fresh water for industrial needs and human consumption is limited.
Various industrial and developmental activities in recent times have resulted in increasing the pollution level and deteriorating the water quality. Water shortages and unreliable water quality are considered major obstacles to achieve sustainable development and improvement in the quality of life. The water
demand in the country is increasing fast due to progressive increase in the demand of water for irrigation, rapid industrialization, and population growth and improving life standards. The existing water resources are diminishing (i) due to unequal distribution of rain water and occasional drought, (ii) excessive exploitation of ground water sources and its insufficient recharge, (iii) deterioration of water quality due to the discharge of domestic and industrial effluents without adequate treatment. This is resulting into water stress/ scarcity. Country is currently passing through social and economic transition.
The proportion of the population which is urban has doubled over the last thirty years (and is now about 30%), agriculture now accounts for about 25% of GDP and the economy has been growing at around 7-9% a year. Country has a highly seasonal pattern of rainfall, with 50% of precipitation falling
in just 15 days and over 90% of river flows in just four months
A Primer On Brackish And Seawater Desalination
Abstract: This publication was produced as an activity of the Texas Living Waters Project. This project
is a collaborative effort of the National Wildlife Federation, Environmental Defense, and the Lone
Star Chapter of the Sierra Club. The goals of the project are to 1) ensure adequate water for people
and environmental needs, 2) reduce future demand for water and foster efficient and sustainable use
of current water supplies, 3) educate the public and decision makers about the impact of wasteful
water use and the opportunities for water conservation, and 4) involve citizens in the decision
making process for water management.
A Primer On Brackish And Seawater Desalination
Abstract: This publication was produced as an activity of the Texas Living Waters Project. This project
is a collaborative effort of the National Wildlife Federation, Environmental Defense, and the Lone
Star Chapter of the Sierra Club. The goals of the project are to 1) ensure adequate water for people
and environmental needs, 2) reduce future demand for water and foster efficient and sustainable use
of current water supplies, 3) educate the public and decision makers about the impact of wasteful
water use and the opportunities for water conservation, and 4) involve citizens in the decision
making process for water management.
Desalination For Safe Water Supply
Preface:
Access to sufficient quantities of safe water for drinking and domestic uses and also for commercial and industrial applications is critical to health and well being, and the opportunity to achieve human and economic development. People in many areas of the world have historically suffered from inadequate access to safe water. Some must walk long distances just to obtain sufficient water to sustain life. As a result they have had to endure health consequences and have not had the opportunity to develop their resources and capabilities to achieve major improvements in their well being. With growth of world population the availability of the limited quantities of fresh water decreases. Desalination technologies were introduced about 50 years ago at and were able to expand access to water, but at high cost. Developments of new and improved technologies have now significantly broadened the opportunities to access major quantities of safe water in many parts of the world. Costs are still significant but there has been a reducing cost trend, and the option is much more widely available. When the alternative is no water or inadequate water greater cost may be endurable in many circumstances.
Desalination For Safe Water Supply
Preface:
Access to sufficient quantities of safe water for drinking and domestic uses and also for commercial and industrial applications is critical to health and well being, and the opportunity to achieve human and economic development. People in many areas of the world have historically suffered from inadequate access to safe water. Some must walk long distances just to obtain sufficient water to sustain life. As a result they have had to endure health consequences and have not had the opportunity to develop their resources and capabilities to achieve major improvements in their well being. With growth of world population the availability of the limited quantities of fresh water decreases. Desalination technologies were introduced about 50 years ago at and were able to expand access to water, but at high cost. Developments of new and improved technologies have now significantly broadened the opportunities to access major quantities of safe water in many parts of the world. Costs are still significant but there has been a reducing cost trend, and the option is much more widely available. When the alternative is no water or inadequate water greater cost may be endurable in many circumstances.
Concentrating Solar Power For Seawater Desalination
Introduction:
The general perception of “solar desalination” today comprises only small scale technologies for decentralized water supply in remote places, which may be quite important for the development of rural areas, but do not address the increasing water deficits of the quickly growing urban centers of demand. Conventional large scale desalination is perceived as expensive, energy consuming and limited to rich countries like those of the Arabian Gulf, especially in view of the quickly escalating cost of fossil fuels like oil, natural gas and coal. The environmental impacts of large scale desalination due to airborne emissions of pollutants from energy consumption and to the discharge of brine and chemical additives to the sea are increasingly considered as critical. For those reasons, most contemporary strategies against a “Global Water Crisis” consider seawater desalination only as a marginal element of supply. The focus of most recommendations lies on more efficient use of water, better accountability, re-use of waste water, enhanced distribution and advanced irrigation systems. To this adds the recommendation to reduce agriculture and rather import food from other places. On the other hand, most sources that do recommend seawater desalination as part of a solution to the water crisis usually propose nuclear fission and fusion as indispensable option.
Concentrating Solar Power For Seawater Desalination
Introduction:
The general perception of “solar desalination” today comprises only small scale technologies for decentralized water supply in remote places, which may be quite important for the development of rural areas, but do not address the increasing water deficits of the quickly growing urban centers of demand. Conventional large scale desalination is perceived as expensive, energy consuming and limited to rich countries like those of the Arabian Gulf, especially in view of the quickly escalating cost of fossil fuels like oil, natural gas and coal. The environmental impacts of large scale desalination due to airborne emissions of pollutants from energy consumption and to the discharge of brine and chemical additives to the sea are increasingly considered as critical. For those reasons, most contemporary strategies against a “Global Water Crisis” consider seawater desalination only as a marginal element of supply. The focus of most recommendations lies on more efficient use of water, better accountability, re-use of waste water, enhanced distribution and advanced irrigation systems. To this adds the recommendation to reduce agriculture and rather import food from other places. On the other hand, most sources that do recommend seawater desalination as part of a solution to the water crisis usually propose nuclear fission and fusion as indispensable option.
Desalination and Membrane Technologies: Federal Research and Adoption Issues
In the United States, desalination and membrane technologies are used to augment municipal water supply, produce high-quality industrial water supplies, and reclaim contaminated supplies (including from oil and gas development). Approximately 2,000 desalination facilities larger than
0.3 million gallons per day (MGD) operate in the United States; this represents more than 2% of U.S. municipal and industrial freshwater use. At issue for Congress is what should be the federal role in supporting desalination and membrane technology research and facilities. Desalination issues before the 114th Congress may include how to focus federal research, at what level to support desalination research and projects, and how to provide a regulatory context that protects the environment and public health without disadvantaging desalination’s adoption.
Desalination and Membrane Technologies: Federal Research and Adoption Issues
In the United States, desalination and membrane technologies are used to augment municipal water supply, produce high-quality industrial water supplies, and reclaim contaminated supplies (including from oil and gas development). Approximately 2,000 desalination facilities larger than
0.3 million gallons per day (MGD) operate in the United States; this represents more than 2% of U.S. municipal and industrial freshwater use. At issue for Congress is what should be the federal role in supporting desalination and membrane technology research and facilities. Desalination issues before the 114th Congress may include how to focus federal research, at what level to support desalination research and projects, and how to provide a regulatory context that protects the environment and public health without disadvantaging desalination’s adoption.
California Desalination Planning Handbook
Introduction:
Desalination is receiving increased attention as a means for addressing the water supply challenges of California. Growing population, much of which is located in semi-arid regions of the state, and various other water demands pose increased pressure on existing water supplies. Much of California’s water supply depends on snow accumulation in the winter, providing spring runoff that flls reservoirs and replenishes often depleted groundwater supplies. But in periods of drought, water supply shortages can be encountered throughout the state, particularly in the central valley and southern portion of the state. All indications suggest the impacts of global warming will include a change in the timing of runoff and less snowfall. This will put more pressure on existing supplies, and exacerbate the impacts of drought. As the implications of global warming become clearer, more emphasis will likely be given to developing
new sources of water supply to meet existing and projected demand. While conservation and recycling are recommended as the frst course of action, other alternatives (such as desalination and increased surface and groundwater storage) are receiving increased attention.
California Desalination Planning Handbook
Introduction:
Desalination is receiving increased attention as a means for addressing the water supply challenges of California. Growing population, much of which is located in semi-arid regions of the state, and various other water demands pose increased pressure on existing water supplies. Much of California’s water supply depends on snow accumulation in the winter, providing spring runoff that flls reservoirs and replenishes often depleted groundwater supplies. But in periods of drought, water supply shortages can be encountered throughout the state, particularly in the central valley and southern portion of the state. All indications suggest the impacts of global warming will include a change in the timing of runoff and less snowfall. This will put more pressure on existing supplies, and exacerbate the impacts of drought. As the implications of global warming become clearer, more emphasis will likely be given to developing
new sources of water supply to meet existing and projected demand. While conservation and recycling are recommended as the frst course of action, other alternatives (such as desalination and increased surface and groundwater storage) are receiving increased attention.
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