Influence Of Hydrophobization Conditions And Ceramic Membranes Pore Size On Their Properties In Vacuum Membrane Distillation Of Water–Organic Solvent Mixtures
Source: https://www.elsevier.com
Author: Wojciech Kujawski , Joanna Kujawa , Ewa Wierzbowska , Sophie Cerneaux , Marek Bryjak , Jan Kujawski
The initially hydrophilic micro- and macroporous ceramic membranes were successfully hydrophobized by grafting with fluoroalkylsilane (FAS) molecules. The influence of diverse parameters (e.g. type of molecule, duration of grafting, concentration of FAS solution, type of solvent) on the resulting hydrophobic surface was investigated.
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Comparison of Wastewater Treatment Using Activated Carbon from Bamboo and Oil Palm
Abstract
Developing country causes growth of industries sectors. Despite that industrial sectors releases massive amount of waste water into the environment. At the same time, the increasing number of vehicles in Malaysia promotes the development of automobile workshop that produces huge amount of wastewater as well. Wastewater contains high level of suspended total solids and leave untreated. For instance oil, grease, dyestuff, chromium, phosphate in washing products and colouring, as well as heavy metals such as lead, cadmium, barium and others potential metals. All these hazardous wastes directly pollute the environment especially the groundwater and harm the ecosystem. In order to minimize and reduce the impact to the environment, the wastewater needed to be treated using technology such as permeable reactive barrier (PRB). Activated carbon is one of the PRB utilised. It is a compromised material for treatment of wastewater where there are varieties of sources to produce activated carbon. Malaysia as an active agricultural country, massive amount of agriculture wastes can be turned into activated carbon. They are two methods used to produce activated carbon, namely furnace heat processing and microwave processing. The usage of furnace and microwave instruments can produce different quality of activated carbon due to different mechanism involves. Furnace heat processing transferred the heat from external to the internal but microwave processing is vice versa. In this article, a brief overview of activated carbon usage for wastewater treatment is highlighted.
Comparison of Wastewater Treatment Using Activated Carbon from Bamboo and Oil Palm
Abstract
Developing country causes growth of industries sectors. Despite that industrial sectors releases massive amount of waste water into the environment. At the same time, the increasing number of vehicles in Malaysia promotes the development of automobile workshop that produces huge amount of wastewater as well. Wastewater contains high level of suspended total solids and leave untreated. For instance oil, grease, dyestuff, chromium, phosphate in washing products and colouring, as well as heavy metals such as lead, cadmium, barium and others potential metals. All these hazardous wastes directly pollute the environment especially the groundwater and harm the ecosystem. In order to minimize and reduce the impact to the environment, the wastewater needed to be treated using technology such as permeable reactive barrier (PRB). Activated carbon is one of the PRB utilised. It is a compromised material for treatment of wastewater where there are varieties of sources to produce activated carbon. Malaysia as an active agricultural country, massive amount of agriculture wastes can be turned into activated carbon. They are two methods used to produce activated carbon, namely furnace heat processing and microwave processing. The usage of furnace and microwave instruments can produce different quality of activated carbon due to different mechanism involves. Furnace heat processing transferred the heat from external to the internal but microwave processing is vice versa. In this article, a brief overview of activated carbon usage for wastewater treatment is highlighted.
Engineered Nanomaterials for Water Treatment and Remediation
Water is one of the world’s most abundant resources, but less than 1% of the global supply of water is available and safe for human consumption [1]. According to the World Health Organization, over 760 million people were without adequate drinking water supply in 2011 [2]. Where it is available, the cost of potable water is rising due to increasing energy costs, growing populations, and climatic or other environmental issues [1,3]. In addition, an increasing number of drinking water sources are showing evidence of contamination, especially by emerging pollutants like pharmaceuticals and personal care products [4,5]. Many traditional water and wastewater treatment methods do not effectively remove these emerging contaminants, and/or are not capable of removing enough to meet increasingly stringent water quality standards [5,6]. Contamination of surface waters also constitutes a risk to water supplies because pollutants may penetrate into aquifers, where they can be transported to drinking water sources.
Engineered Nanomaterials for Water Treatment and Remediation
Water is one of the world’s most abundant resources, but less than 1% of the global supply of water is available and safe for human consumption [1]. According to the World Health Organization, over 760 million people were without adequate drinking water supply in 2011 [2]. Where it is available, the cost of potable water is rising due to increasing energy costs, growing populations, and climatic or other environmental issues [1,3]. In addition, an increasing number of drinking water sources are showing evidence of contamination, especially by emerging pollutants like pharmaceuticals and personal care products [4,5]. Many traditional water and wastewater treatment methods do not effectively remove these emerging contaminants, and/or are not capable of removing enough to meet increasingly stringent water quality standards [5,6]. Contamination of surface waters also constitutes a risk to water supplies because pollutants may penetrate into aquifers, where they can be transported to drinking water sources.
Removal of Escherichia Coli from Domestic Wastewater Using Electrocoagulation
ABSTRACT
The objective of this study was to evaluate the efficiency of electrocoagulation in the removal of Escherichia coli from domestic and urban wastewaters and to determine the effects of the main operational parameters on the process. An electrocoagulation reactor with aluminum and iron electrodes was built for this purpose. A factorial design was applied, where amperage, treatment time, and pH were considered as the factors and E. coli percent removal was the response variable. After 20 min of treatment, >97% removal efficiency was achieved. The highest E. coli removal efficiency achieved was 99.9% at a neutral pH of 7, amperage of 3 A, and treatment time of 60 min. However, the removal efficiency of close to 99% was also achieved at natural wastewater pH of 8.5. The statistical analyses showed that the three tested factors significantly affected the E. coli removal percentage (p < 0.05). These results indicate that electrocoagulation has a high disinfection power in a primary reactor in removing water con[1]taminants as well as simultaneously removing pathogenic microorganisms when compared to biological treatment processes. This represents an additional benefit, because it will considerably reduce the use of chlorine during the final disinfection stage.
Removal of Escherichia Coli from Domestic Wastewater Using Electrocoagulation
ABSTRACT
The objective of this study was to evaluate the efficiency of electrocoagulation in the removal of Escherichia coli from domestic and urban wastewaters and to determine the effects of the main operational parameters on the process. An electrocoagulation reactor with aluminum and iron electrodes was built for this purpose. A factorial design was applied, where amperage, treatment time, and pH were considered as the factors and E. coli percent removal was the response variable. After 20 min of treatment, >97% removal efficiency was achieved. The highest E. coli removal efficiency achieved was 99.9% at a neutral pH of 7, amperage of 3 A, and treatment time of 60 min. However, the removal efficiency of close to 99% was also achieved at natural wastewater pH of 8.5. The statistical analyses showed that the three tested factors significantly affected the E. coli removal percentage (p < 0.05). These results indicate that electrocoagulation has a high disinfection power in a primary reactor in removing water con[1]taminants as well as simultaneously removing pathogenic microorganisms when compared to biological treatment processes. This represents an additional benefit, because it will considerably reduce the use of chlorine during the final disinfection stage.
Renewable Energy-Driven Desalination: New Trends And Future Prospects Of Small Capacity Systems
Abstract:
New trends and future prospects for small capacity systems of Renewable Energy-driven Desalination (REDES) are reviewed and assessed in this paper over a nominal desalination capacity range of 3–1000 m3/d. A thorough literature review is reported in order to evaluate current research and developing activities. Outstanding commercial prospects in the near future are identified for two off-grid REDES technologies under development. First, wave energy converters with direct coupling to seawater desalination. Second, solar micro gas turbines with biofuel backup coupled to reverse osmosis (RO) desalination and/or zero liquid discharge water treatment. These systems, as well as mature REDES plants (namely PV/RO and wind turbines/RO), will benefit from forthcoming advances in energy efficiency in the RO process itself. The Closed Circuit RO desalination (CCROTM) concept may be a key configuration for enhancing RE-driven RO desalination. Additionally, opportunities for innovation in seawater RO desalination with variable power consumption are highlighted. On the other hand, our conclusions highlight opportunities for developing novel portable REDES systems based on solar membrane distillation with a portable linear Fresnel concentrator manufactured by SOLATOM. Additionally, the concept of portable systems could foster the commercial development of microbial desalination cells combined with solar PV energy and RO powered by tidal currents.
Renewable Energy-Driven Desalination: New Trends And Future Prospects Of Small Capacity Systems
Abstract:
New trends and future prospects for small capacity systems of Renewable Energy-driven Desalination (REDES) are reviewed and assessed in this paper over a nominal desalination capacity range of 3–1000 m3/d. A thorough literature review is reported in order to evaluate current research and developing activities. Outstanding commercial prospects in the near future are identified for two off-grid REDES technologies under development. First, wave energy converters with direct coupling to seawater desalination. Second, solar micro gas turbines with biofuel backup coupled to reverse osmosis (RO) desalination and/or zero liquid discharge water treatment. These systems, as well as mature REDES plants (namely PV/RO and wind turbines/RO), will benefit from forthcoming advances in energy efficiency in the RO process itself. The Closed Circuit RO desalination (CCROTM) concept may be a key configuration for enhancing RE-driven RO desalination. Additionally, opportunities for innovation in seawater RO desalination with variable power consumption are highlighted. On the other hand, our conclusions highlight opportunities for developing novel portable REDES systems based on solar membrane distillation with a portable linear Fresnel concentrator manufactured by SOLATOM. Additionally, the concept of portable systems could foster the commercial development of microbial desalination cells combined with solar PV energy and RO powered by tidal currents.
Sludge Biotic Index
Abstract
This study aimed to determine the relationship between activated sludge microfauna, the sludge biotic index (SBI) and the effluent quality of a full-scale municipal wastewater treatment plant (WWTP) working with shock organic and ammonium loadings caused by periodic wastewater delivery from septic tanks. Irrespective of high/low effluent quality in terms of COD, BOD5, ammonium and suspended solids, high SBI values (8–10), which correspond to the first quality class of sludge, were observed. High SBI values were connected with abundant taxonomic composition and the domination of crawling ciliates with shelled amoebae and attached ciliates. High SBI values, even at a low effluent quality, limit the usefulness of the index for monitoring the status of an activated sludge system and the effluent quality in municipal WWTP-treated wastewater from septic tanks. It was shown that a more sensitive indicator of effluent quality was a change in the abundance of attached ciliates with a narrow peristome (Vorticella infusionum and Opercularia coarctata), small flagellates and crawling ciliates (Acineria uncinata) feeding on flagellates.
Sludge Biotic Index
Abstract
This study aimed to determine the relationship between activated sludge microfauna, the sludge biotic index (SBI) and the effluent quality of a full-scale municipal wastewater treatment plant (WWTP) working with shock organic and ammonium loadings caused by periodic wastewater delivery from septic tanks. Irrespective of high/low effluent quality in terms of COD, BOD5, ammonium and suspended solids, high SBI values (8–10), which correspond to the first quality class of sludge, were observed. High SBI values were connected with abundant taxonomic composition and the domination of crawling ciliates with shelled amoebae and attached ciliates. High SBI values, even at a low effluent quality, limit the usefulness of the index for monitoring the status of an activated sludge system and the effluent quality in municipal WWTP-treated wastewater from septic tanks. It was shown that a more sensitive indicator of effluent quality was a change in the abundance of attached ciliates with a narrow peristome (Vorticella infusionum and Opercularia coarctata), small flagellates and crawling ciliates (Acineria uncinata) feeding on flagellates.
Overview Of The Main Disinfection Processes For Wastewater And Drinking water Treatment Plants
Abstract: The use of water disinfection as a public health measure reduces the spread of diseases. Various disinfection technologies can be used to meet the pathogen inactivation demand in water. This work is an overview of the main disinfection technologies of wastewater and drinking water that reports for the conventional processes the action mechanism, the possible formation of by-products, the operative conditions, the advantages and disadvantages. For advanced and natural processes the action mechanisms are reported. Advanced technologies are interesting but are still in the research state, while conventional technologies are the most used. There is a tendency, especially in Italy, to use chlorine-based disinfectant, despite in some forms could lead to production of disinfection by-products.
Overview Of The Main Disinfection Processes For Wastewater And Drinking water Treatment Plants
Abstract: The use of water disinfection as a public health measure reduces the spread of diseases. Various disinfection technologies can be used to meet the pathogen inactivation demand in water. This work is an overview of the main disinfection technologies of wastewater and drinking water that reports for the conventional processes the action mechanism, the possible formation of by-products, the operative conditions, the advantages and disadvantages. For advanced and natural processes the action mechanisms are reported. Advanced technologies are interesting but are still in the research state, while conventional technologies are the most used. There is a tendency, especially in Italy, to use chlorine-based disinfectant, despite in some forms could lead to production of disinfection by-products.
Governance of Artificial Intelligence in Water and Wastewater Management: The Case Study of Japan
Abstract:
The integration of artificial intelligence into various aspects of daily life is developing at a rapid pace in Japan. Discussions to govern applications of artificial intelligence to the field of social infrastructure are also critical and need to match the rapid pace of development. However, the legal implications and risks of applying artificial intelligence to the management of lifelines such as drinking water supply and wastewater treatment have not yet been fully explored. This paper reviews the existing legislations and ongoing discussions on governance regarding applications of artificial intelligence to water and wastewater management. Based on the review, we discuss the ability of legislative frameworks in Japan to respond to the applications of artificial intelligence, as well as identifying potential gaps and challenges thereof, including access to accurate data, demarcation of rights and responsibilities, risk hedging and risk management, monitoring and evaluation, and handling of intellectual property rights. This paper concludes with key recommendations to national and local governments to support the application of artificial intelligence in the field of water and wastewater.
Governance of Artificial Intelligence in Water and Wastewater Management: The Case Study of Japan
Abstract:
The integration of artificial intelligence into various aspects of daily life is developing at a rapid pace in Japan. Discussions to govern applications of artificial intelligence to the field of social infrastructure are also critical and need to match the rapid pace of development. However, the legal implications and risks of applying artificial intelligence to the management of lifelines such as drinking water supply and wastewater treatment have not yet been fully explored. This paper reviews the existing legislations and ongoing discussions on governance regarding applications of artificial intelligence to water and wastewater management. Based on the review, we discuss the ability of legislative frameworks in Japan to respond to the applications of artificial intelligence, as well as identifying potential gaps and challenges thereof, including access to accurate data, demarcation of rights and responsibilities, risk hedging and risk management, monitoring and evaluation, and handling of intellectual property rights. This paper concludes with key recommendations to national and local governments to support the application of artificial intelligence in the field of water and wastewater.
Adsorption of Heavy Metal Ions from Aqueous Solutions onto Rice Husk Ash Low Cost Adsorbent
Abstract
In the present study, adsorption of Zn (II), Cd (II) and Hg (II) ions on rice husk ash (RHA) has been investigated in single, binary and tertiary systems.
Batch experiments were also carried out for mono-and multi-component systems with varying metal ions concentrations (mg/l) to investigate the competitive adsorption characteristics.
Adsorption of Heavy Metal Ions from Aqueous Solutions onto Rice Husk Ash Low Cost Adsorbent
Abstract
In the present study, adsorption of Zn (II), Cd (II) and Hg (II) ions on rice husk ash (RHA) has been investigated in single, binary and tertiary systems.
Batch experiments were also carried out for mono-and multi-component systems with varying metal ions concentrations (mg/l) to investigate the competitive adsorption characteristics.
A Pilot Study of an Electromagnetic Field for Control of Reverse Osmosis Membrane Fouling and Scaling During Brackish Groundwater Desalination
Abstract: This study investigated the effects of an electromagnetic field (EMF) on control of membrane
fouling and scaling during desalination of brackish groundwater using a pilot reverse osmosis (RO)
skid. The groundwater was primarily CaSO4 type with a total dissolved solids concentration of
5850 mg/L and hardness of 2500 mg/L as CaCO3. Two EMF devices were installed in the pipeline
before a cartridge filter and in the RO feed inlet to induce an electric signal of ±150 kHz to the
groundwater. The effects of EMF on membrane scaling were evaluated under accelerated conditions,
i.e., without pH adjustment and addition of antiscalant. Two-phase experiments were conducted:
Phase 1 (376 h) with the EMF devices turned on after 150 h baseline operation; and Phase 2 (753 h)
with the EMF devices turned on from the beginning of testing. The EMF significantly reduced
membrane scaling and improved RO performance by 38.3% and 14.3% in terms of normalized water
permeability decline rate after 150 h and 370 h operation, respectively. Membrane autopsy results
indicated that the fouling layer formed under the influence of EMF was loose with a low density and
was easily removed by hydraulic flushing
A Pilot Study of an Electromagnetic Field for Control of Reverse Osmosis Membrane Fouling and Scaling During Brackish Groundwater Desalination
Abstract: This study investigated the effects of an electromagnetic field (EMF) on control of membrane
fouling and scaling during desalination of brackish groundwater using a pilot reverse osmosis (RO)
skid. The groundwater was primarily CaSO4 type with a total dissolved solids concentration of
5850 mg/L and hardness of 2500 mg/L as CaCO3. Two EMF devices were installed in the pipeline
before a cartridge filter and in the RO feed inlet to induce an electric signal of ±150 kHz to the
groundwater. The effects of EMF on membrane scaling were evaluated under accelerated conditions,
i.e., without pH adjustment and addition of antiscalant. Two-phase experiments were conducted:
Phase 1 (376 h) with the EMF devices turned on after 150 h baseline operation; and Phase 2 (753 h)
with the EMF devices turned on from the beginning of testing. The EMF significantly reduced
membrane scaling and improved RO performance by 38.3% and 14.3% in terms of normalized water
permeability decline rate after 150 h and 370 h operation, respectively. Membrane autopsy results
indicated that the fouling layer formed under the influence of EMF was loose with a low density and
was easily removed by hydraulic flushing
Artificial Neural Network Model for the Prediction of Groundwater Quality
The present article delves into the examination of groundwater quality, based on WQI, for drinking purposes in Baghdad City. Further, for carrying out the investigation, the data was collected from the Ministry of Water Resources of Baghdad, which represents water samples drawn from 114 wells in Al-Karkh and Al-Rusafa sides of Baghdad city. With the aim of further determining WQI, four water parameters such as (i) pH, (ii) Chloride (Cl), (iii) Sulfate (SO4), and (iv) Total dissolved solids (TDS), were taken into consideration. Additionally, to anticipate changes in groundwater WQI, IBM® SPSS® Statistics 19 software (SPSS) was used to develop an artificial neural network model (ANNM). With the application of this ANNM model, the results obtained illustrated high prediction efficiency, as the sum of squares error functions (for training and testing samples) and coefficient of determination (R2), were found to be (0.038 and 0.005) and 0.973, respectively.
Artificial Neural Network Model for the Prediction of Groundwater Quality
The present article delves into the examination of groundwater quality, based on WQI, for drinking purposes in Baghdad City. Further, for carrying out the investigation, the data was collected from the Ministry of Water Resources of Baghdad, which represents water samples drawn from 114 wells in Al-Karkh and Al-Rusafa sides of Baghdad city. With the aim of further determining WQI, four water parameters such as (i) pH, (ii) Chloride (Cl), (iii) Sulfate (SO4), and (iv) Total dissolved solids (TDS), were taken into consideration. Additionally, to anticipate changes in groundwater WQI, IBM® SPSS® Statistics 19 software (SPSS) was used to develop an artificial neural network model (ANNM). With the application of this ANNM model, the results obtained illustrated high prediction efficiency, as the sum of squares error functions (for training and testing samples) and coefficient of determination (R2), were found to be (0.038 and 0.005) and 0.973, respectively.
Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures
Biofouling is a critical issue in membrane water and wastewater treatment as it greatly compromises the efficiency of the treatment processes. It is difficult to control, and significant economic resources have been dedicated to the development of effective biofouling monitoring and control strategies. This paper highlights the underlying causes of membrane biofouling and provides a review on recent developments of potential monitoring and control methods in water and wastewater treatment with the aim of identifying the remaining issues and challenges in this area.
Biofouling of Water Treatment Membranes: A Review of the Underlying Causes, Monitoring Techniques and Control Measures
Biofouling is a critical issue in membrane water and wastewater treatment as it greatly compromises the efficiency of the treatment processes. It is difficult to control, and significant economic resources have been dedicated to the development of effective biofouling monitoring and control strategies. This paper highlights the underlying causes of membrane biofouling and provides a review on recent developments of potential monitoring and control methods in water and wastewater treatment with the aim of identifying the remaining issues and challenges in this area.
Analysis of the Flux Performance of Different RO/NF Membranes in the Treatment of Agroindustrial Wastewater by Means of the Boundary Flux Theory
Abstract:
Dynamic membrane system behaviour must be adequately addressed to avoid process unfeasibility. The lack of proper analysis will mean relying on erroneous permeate flux values in the system design, which will lead to quick and/or steady high fouling rates. In this paper, the authors present additional data supporting the boundary flux theory as a helpful tool for membrane engineers to carefully avoid process failures. By fitting the dynamic permeate flux data to the
boundary flux model, it was possible to calculate the β fouling index for the three selected membranes (one nanofiltration (NF) and two reverse osmosis (RO) ones). The dynamic flux given by the low-pressure RO membrane did not follow sub-boundary operating conditions, since a sharp flux loss was measured throughout the whole operating cycle, pinpointing that supra-boundary flux conditions were governing the system. This was supported by the calculated value of the β fouling parameter, which resulted to be in the order of ten times higher for this membrane. However, the values of β→0 for the SC-RO and DK-NF ones, supported by the very low value of the sub-boundary fouling parameter α (0.002 and 0.007 L·h −1·m−2 ·bar−2 , respectively), ensure nearly boundary operating conditions for these membranes.
Analysis of the Flux Performance of Different RO/NF Membranes in the Treatment of Agroindustrial Wastewater by Means of the Boundary Flux Theory
Abstract:
Dynamic membrane system behaviour must be adequately addressed to avoid process unfeasibility. The lack of proper analysis will mean relying on erroneous permeate flux values in the system design, which will lead to quick and/or steady high fouling rates. In this paper, the authors present additional data supporting the boundary flux theory as a helpful tool for membrane engineers to carefully avoid process failures. By fitting the dynamic permeate flux data to the
boundary flux model, it was possible to calculate the β fouling index for the three selected membranes (one nanofiltration (NF) and two reverse osmosis (RO) ones). The dynamic flux given by the low-pressure RO membrane did not follow sub-boundary operating conditions, since a sharp flux loss was measured throughout the whole operating cycle, pinpointing that supra-boundary flux conditions were governing the system. This was supported by the calculated value of the β fouling parameter, which resulted to be in the order of ten times higher for this membrane. However, the values of β→0 for the SC-RO and DK-NF ones, supported by the very low value of the sub-boundary fouling parameter α (0.002 and 0.007 L·h −1·m−2 ·bar−2 , respectively), ensure nearly boundary operating conditions for these membranes.
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