Towards Promotion of Reverse Osmosis Process Efficiency, Cost Effectiveness and Environmental Safety
Towards Promotion of Reverse Osmosis Process Efficiency, Cost Effectiveness and Environmental Safety
Presented by: Prof Dr M. Gamal Khedr
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Desalination Plant Basis Of Design
Overview:
The project potable water requirements will be provided using single desalination plant with the Grand Bahama Port Authority water supply serving as the backup source. The overall desalination treatment process will consist of feedwater pumping, bag filtration, optional media filtration, the addition of a scale
inhibitor, cartridge filtration, membrane separation, forced air degasification, re-pumping, and post treatment. Provisions have been included to bypass the post treatment systems for the production of irrigation water. The post aeration re-pump station will be designed to transfer either type of water to the
appropriate storage tanks located within the project. Membrane concentrate will be disposed via an injection well to be constructed as part of this project.
The desalination process will consist of a dual treatment units or “trains” each equipped with a positive displacement axial piston first pass membrane feed pump, first pass membrane array, energy recovery system, second pass membrane feed pump, second pass membrane array, high- and low-pressure
piping and instrumentation. The second pass system is designed to treat up to 60 percent of the first pass permeate. A membrane cleaning/flush system will be provided. The membrane post treatment will be designed to receive the flow from both units and consists of a forced air degasified, repumping, recarbonation, calcium carbonate up flow contactors to boost finished water hardness and alkalinity concentrations; and three chemical feed systems for the metering of a corrosion inhibitor, dilute hydrochloric acid for pH adjustment and sodium hypochlorite for residual disinfection. The final pH and chlorine residual will be controlled and recorded by a separate system. The following sections describe the various aspects of the facility in greater detail. Process flow
schematics are presented in Appendix A.
Desalination Plant Basis Of Design
Overview:
The project potable water requirements will be provided using single desalination plant with the Grand Bahama Port Authority water supply serving as the backup source. The overall desalination treatment process will consist of feedwater pumping, bag filtration, optional media filtration, the addition of a scale
inhibitor, cartridge filtration, membrane separation, forced air degasification, re-pumping, and post treatment. Provisions have been included to bypass the post treatment systems for the production of irrigation water. The post aeration re-pump station will be designed to transfer either type of water to the
appropriate storage tanks located within the project. Membrane concentrate will be disposed via an injection well to be constructed as part of this project.
The desalination process will consist of a dual treatment units or “trains” each equipped with a positive displacement axial piston first pass membrane feed pump, first pass membrane array, energy recovery system, second pass membrane feed pump, second pass membrane array, high- and low-pressure
piping and instrumentation. The second pass system is designed to treat up to 60 percent of the first pass permeate. A membrane cleaning/flush system will be provided. The membrane post treatment will be designed to receive the flow from both units and consists of a forced air degasified, repumping, recarbonation, calcium carbonate up flow contactors to boost finished water hardness and alkalinity concentrations; and three chemical feed systems for the metering of a corrosion inhibitor, dilute hydrochloric acid for pH adjustment and sodium hypochlorite for residual disinfection. The final pH and chlorine residual will be controlled and recorded by a separate system. The following sections describe the various aspects of the facility in greater detail. Process flow
schematics are presented in Appendix A.
Tailoring Advanced Desalination Technologies for 21st Century Agriculture
Abstract: Substantial parts of the U.S., particularly drier landlocked regions, are facing acute water shortages and water quality issues that decrease agricultural productivity. Reduced crop yields cause billions of dollars in losses annually, affecting the livelihoods of thousands. A combination of population growth, inefficient agricultural practices, and resource demanding consumption trends is only expected to increase pressure on our water supplies. This research proposal seeks to address water and food security issues by cost-effectively and energy-efficiently enhancing water quality and water supply in greenhouses; a $22.93 billion dollar industry in 2017 that is rapidly growing at an annual rate of 8.92%. Greenhouses widely practice desalination of salty irrigation water to improve their operations. However, currently used desalination methods do not tailor greenhouse waters based on crop requirements. This work investigates a fully integrated desalination solution that treats and tailors brackish source waters ingreenhouses to save fertilizer and water. Specifically, this project experimentally studies multi-ion transport in and assesses the economic viable of monovalent selective electrodialysis (MSED). MSED allows for the selective removal of monovalent ions damaging to crops and the retention of divalent ions beneficial for crops, unlike the widely used reverse osmosis (RO), which removes all ions from greenhouse source water. First, we evaluate the techno-economic feasibility of MSED compared to other brackish desalination technologies for agricultural applications, based on primary market research we conduct with over 70 greenhouses.
These include conventional technologies, such as reverse osmosis (RO) and electrodialysis (ED), and advanced technologies, such as closed circuit reverse osmosis (CCRO). The analysis determines the levelized costs of water, the capital costs and energy requirements of these technologies, and how these vary with feed salinity, system capacity and recovery ratio. Then, we build a bench-scale setup to experientially characterize MSED membrane properties, including monovalent selectivity, ion transport, limiting current and resistance, for multiple brackish feedwaters and for two sets of MSED membranes: the widely used Neosepta ACS/CMS membranes and the new Fujifilm Type 16 membranes. Both MSED membranes show notable monovalent selectivity for all tested compositions, reflecting the potential of the technology for selective desalination in greenhouses. The measurements are compared to a model for MSED in multi-ion solutions. The model predicts multi-ion transport for the Neosepta and Fujifilm MSED systems within 6% and 8%, respectively.
Tailoring Advanced Desalination Technologies for 21st Century Agriculture
Abstract: Substantial parts of the U.S., particularly drier landlocked regions, are facing acute water shortages and water quality issues that decrease agricultural productivity. Reduced crop yields cause billions of dollars in losses annually, affecting the livelihoods of thousands. A combination of population growth, inefficient agricultural practices, and resource demanding consumption trends is only expected to increase pressure on our water supplies. This research proposal seeks to address water and food security issues by cost-effectively and energy-efficiently enhancing water quality and water supply in greenhouses; a $22.93 billion dollar industry in 2017 that is rapidly growing at an annual rate of 8.92%. Greenhouses widely practice desalination of salty irrigation water to improve their operations. However, currently used desalination methods do not tailor greenhouse waters based on crop requirements. This work investigates a fully integrated desalination solution that treats and tailors brackish source waters ingreenhouses to save fertilizer and water. Specifically, this project experimentally studies multi-ion transport in and assesses the economic viable of monovalent selective electrodialysis (MSED). MSED allows for the selective removal of monovalent ions damaging to crops and the retention of divalent ions beneficial for crops, unlike the widely used reverse osmosis (RO), which removes all ions from greenhouse source water. First, we evaluate the techno-economic feasibility of MSED compared to other brackish desalination technologies for agricultural applications, based on primary market research we conduct with over 70 greenhouses.
These include conventional technologies, such as reverse osmosis (RO) and electrodialysis (ED), and advanced technologies, such as closed circuit reverse osmosis (CCRO). The analysis determines the levelized costs of water, the capital costs and energy requirements of these technologies, and how these vary with feed salinity, system capacity and recovery ratio. Then, we build a bench-scale setup to experientially characterize MSED membrane properties, including monovalent selectivity, ion transport, limiting current and resistance, for multiple brackish feedwaters and for two sets of MSED membranes: the widely used Neosepta ACS/CMS membranes and the new Fujifilm Type 16 membranes. Both MSED membranes show notable monovalent selectivity for all tested compositions, reflecting the potential of the technology for selective desalination in greenhouses. The measurements are compared to a model for MSED in multi-ion solutions. The model predicts multi-ion transport for the Neosepta and Fujifilm MSED systems within 6% and 8%, respectively.
Chemical Cleaning Effects On Properties And Separation Efciency Of An RO Membrane
Abstract: This study aims to investigate the impacts of chemical cleaning on the performance of a reverse osmosis
membrane. Chemicals used for simulating membrane cleaning include a surfactant (sodium dodecyl sulfate, SDS), a
chelating agent (ethylenediaminetetraacetic acid, EDTA), and two proprietary cleaning formulations namely MC3
and MC11. The impact of sequential exposure to multiple membrane cleaning solutions was also examined. Water
permeability and the rejection of boron and sodium were investigated under various water fluxes, temperatures and
feedwater pH. Changes in the membrane performance were systematically explained based on the changes in the
charge density, hydrophobicity and chemical structure of the membrane surface. The experimental results show that
membrane cleaning can significantly alter the hydrophobicity and water permeability of the membrane; however, its
impacts on the rejections of boron and sodium are marginal. Although the presence of surfactant or chelating agent
may cause decreases in the rejection, solution pH is the key factor responsible for the loss of membrane separation
and changes in the surface properties. The impact of solution pH on the water permeability can be reversed by
applying a subsequent cleaning with the opposite pH condition. Nevertheless, the impacts of solution pH on boron
and sodium rejections are irreversible in most cases
Chemical Cleaning Effects On Properties And Separation Efciency Of An RO Membrane
Abstract: This study aims to investigate the impacts of chemical cleaning on the performance of a reverse osmosis
membrane. Chemicals used for simulating membrane cleaning include a surfactant (sodium dodecyl sulfate, SDS), a
chelating agent (ethylenediaminetetraacetic acid, EDTA), and two proprietary cleaning formulations namely MC3
and MC11. The impact of sequential exposure to multiple membrane cleaning solutions was also examined. Water
permeability and the rejection of boron and sodium were investigated under various water fluxes, temperatures and
feedwater pH. Changes in the membrane performance were systematically explained based on the changes in the
charge density, hydrophobicity and chemical structure of the membrane surface. The experimental results show that
membrane cleaning can significantly alter the hydrophobicity and water permeability of the membrane; however, its
impacts on the rejections of boron and sodium are marginal. Although the presence of surfactant or chelating agent
may cause decreases in the rejection, solution pH is the key factor responsible for the loss of membrane separation
and changes in the surface properties. The impact of solution pH on the water permeability can be reversed by
applying a subsequent cleaning with the opposite pH condition. Nevertheless, the impacts of solution pH on boron
and sodium rejections are irreversible in most cases
California Desalination Planning Handbook
Introduction:
Desalination is receiving increased attention as a means for addressing the water supply challenges of California. Growing population, much of which is located in semi-arid regions of the state, and various other water demands pose increased pressure on existing water supplies. Much of California’s water supply depends on snow accumulation in the winter, providing spring runoff that flls reservoirs and replenishes often depleted groundwater supplies. But in periods of drought, water supply shortages can be encountered throughout the state, particularly in the central valley and southern portion of the state. All indications suggest the impacts of global warming will include a change in the timing of runoff and less snowfall. This will put more pressure on existing supplies, and exacerbate the impacts of drought. As the implications of global warming become clearer, more emphasis will likely be given to developing
new sources of water supply to meet existing and projected demand. While conservation and recycling are recommended as the frst course of action, other alternatives (such as desalination and increased surface and groundwater storage) are receiving increased attention.
California Desalination Planning Handbook
Introduction:
Desalination is receiving increased attention as a means for addressing the water supply challenges of California. Growing population, much of which is located in semi-arid regions of the state, and various other water demands pose increased pressure on existing water supplies. Much of California’s water supply depends on snow accumulation in the winter, providing spring runoff that flls reservoirs and replenishes often depleted groundwater supplies. But in periods of drought, water supply shortages can be encountered throughout the state, particularly in the central valley and southern portion of the state. All indications suggest the impacts of global warming will include a change in the timing of runoff and less snowfall. This will put more pressure on existing supplies, and exacerbate the impacts of drought. As the implications of global warming become clearer, more emphasis will likely be given to developing
new sources of water supply to meet existing and projected demand. While conservation and recycling are recommended as the frst course of action, other alternatives (such as desalination and increased surface and groundwater storage) are receiving increased attention.
A Primer On Brackish And Seawater Desalination
Abstract: This publication was produced as an activity of the Texas Living Waters Project. This project
is a collaborative effort of the National Wildlife Federation, Environmental Defense, and the Lone
Star Chapter of the Sierra Club. The goals of the project are to 1) ensure adequate water for people
and environmental needs, 2) reduce future demand for water and foster efficient and sustainable use
of current water supplies, 3) educate the public and decision makers about the impact of wasteful
water use and the opportunities for water conservation, and 4) involve citizens in the decision
making process for water management.
A Primer On Brackish And Seawater Desalination
Abstract: This publication was produced as an activity of the Texas Living Waters Project. This project
is a collaborative effort of the National Wildlife Federation, Environmental Defense, and the Lone
Star Chapter of the Sierra Club. The goals of the project are to 1) ensure adequate water for people
and environmental needs, 2) reduce future demand for water and foster efficient and sustainable use
of current water supplies, 3) educate the public and decision makers about the impact of wasteful
water use and the opportunities for water conservation, and 4) involve citizens in the decision
making process for water management.
Database Of Permitting Practices For Seawater Desalination Concentrate
Abstract:
The purpose of this research project was to identify the discharge information that permitting agencies need and the decision-making process they go through to permit discharge methods in order to help desalination project proponents focus and expedite their permitting efforts.
The project documented seawater reverse osmosis (SWRO) discharge regulatory issues and provided a critical overview of facility discharge-related information required for permitting desalination projects in the United States and selected countries with advanced environmental regulations and experience in implementing seawater desalination projects. Information was gathered from the three key U.S. states (California, Florida, Texas) where interest in SWRO desalination has been highest. Due to the more extensive international experience with SWRO desalination, information was also obtained from the countries of Australia, Israel, and Spain – all countries of significant recent large-scale SWRO desalination projects. Case studies of 11 SWRO plants and analysis of regulatory systems and permitting processes supported detailed definition of the decision-making process to set discharge permit limits, as well as defining environmental and other regulatory issues associated with concentrate regulation.
Database Of Permitting Practices For Seawater Desalination Concentrate
Abstract:
The purpose of this research project was to identify the discharge information that permitting agencies need and the decision-making process they go through to permit discharge methods in order to help desalination project proponents focus and expedite their permitting efforts.
The project documented seawater reverse osmosis (SWRO) discharge regulatory issues and provided a critical overview of facility discharge-related information required for permitting desalination projects in the United States and selected countries with advanced environmental regulations and experience in implementing seawater desalination projects. Information was gathered from the three key U.S. states (California, Florida, Texas) where interest in SWRO desalination has been highest. Due to the more extensive international experience with SWRO desalination, information was also obtained from the countries of Australia, Israel, and Spain – all countries of significant recent large-scale SWRO desalination projects. Case studies of 11 SWRO plants and analysis of regulatory systems and permitting processes supported detailed definition of the decision-making process to set discharge permit limits, as well as defining environmental and other regulatory issues associated with concentrate regulation.
Desalination: A National Perspective
NOTICE:
The project that is the subject of this report was approved by the Governing Board of the National Research Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of Engineering, and the Institute of Medicine. The members of the panel responsible for the report were chosen for their special competences and with regard for appropriate balance.
Support for this study was provided by the U.S. Bureau of Reclamation under Grant No. 06CS811198. Any opinions, findings, conclusions, or recommendations expressed in this publication are those of the author(s) and do not necessarily reflect the views of the organizations or agencies that provided
support for the project.
Desalination: A National Perspective
NOTICE:
The project that is the subject of this report was approved by the Governing Board of the National Research Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of Engineering, and the Institute of Medicine. The members of the panel responsible for the report were chosen for their special competences and with regard for appropriate balance.
Support for this study was provided by the U.S. Bureau of Reclamation under Grant No. 06CS811198. Any opinions, findings, conclusions, or recommendations expressed in this publication are those of the author(s) and do not necessarily reflect the views of the organizations or agencies that provided
support for the project.
Assessment Of Best Available Technologies For Desalination In Rural/Local Areas
Introduction: The Sustainable Water Integrated Management (SWIM) is a European Union(EU)-funded Regional Technical
Assistance Program [1] that “aims at supporting water governance and mainstreaming by promoting sustainable
and equitable water resources management to become a prominent feature of national development policies and
strategies (agriculture, industry, tourism, etc).” [2]
Countries in the south of the Mediterranean are facing increasing water scarcity. This scarcity is driving the need
for augmenting conventional water supply with alternative water sources. Rural and remote areas are particularly
disadvantaged because such areas are often located far away from municipal water supply systems and
conventional water sources, and are often not connected to the electric power grid. There is good potential for
addressing the water scarcity problem in rural and remote areas through sustainable saline water desalination
technologies. Seawater and brackish water desalination are well-established industries comprising a wide variety
of available technologies with decades of accumulated experience. There are many advancements and evolution in
desalination technologies. The numerous technologies and processes available have different characteristics,
advantages and disadvantages that make each suitable for particular market segments or specific niches.
Moreover, much of the cumulative technology experience is related to large urban supply plants that are either
connected to the grid, or are themselves part of large power and desalination cogeneration plants. Rural and
remote areas have special requirements that influence the appropriate selection of technologies. These include
technical requirements related to small-scale application using renewable energy sources, ease of operation and
maintenance, and simple design; requirements dictated by geographical location; as well as socio-economic and
socio-cultural requirements related to the communities that are intended to operate and benefit from the
technology. Successful implementation and long term sustainability (operational and environmental sustainability)
of desalination projects for rural and remote locations requires that all the relevant requirements be identified and
addressed from the earliest stages of the project.
Assessment Of Best Available Technologies For Desalination In Rural/Local Areas
Introduction: The Sustainable Water Integrated Management (SWIM) is a European Union(EU)-funded Regional Technical
Assistance Program [1] that “aims at supporting water governance and mainstreaming by promoting sustainable
and equitable water resources management to become a prominent feature of national development policies and
strategies (agriculture, industry, tourism, etc).” [2]
Countries in the south of the Mediterranean are facing increasing water scarcity. This scarcity is driving the need
for augmenting conventional water supply with alternative water sources. Rural and remote areas are particularly
disadvantaged because such areas are often located far away from municipal water supply systems and
conventional water sources, and are often not connected to the electric power grid. There is good potential for
addressing the water scarcity problem in rural and remote areas through sustainable saline water desalination
technologies. Seawater and brackish water desalination are well-established industries comprising a wide variety
of available technologies with decades of accumulated experience. There are many advancements and evolution in
desalination technologies. The numerous technologies and processes available have different characteristics,
advantages and disadvantages that make each suitable for particular market segments or specific niches.
Moreover, much of the cumulative technology experience is related to large urban supply plants that are either
connected to the grid, or are themselves part of large power and desalination cogeneration plants. Rural and
remote areas have special requirements that influence the appropriate selection of technologies. These include
technical requirements related to small-scale application using renewable energy sources, ease of operation and
maintenance, and simple design; requirements dictated by geographical location; as well as socio-economic and
socio-cultural requirements related to the communities that are intended to operate and benefit from the
technology. Successful implementation and long term sustainability (operational and environmental sustainability)
of desalination projects for rural and remote locations requires that all the relevant requirements be identified and
addressed from the earliest stages of the project.
An Introduction To Membrane Techniques For Water Desalination
This course is adapted from the Unified Facilities Criteria of the United States government, which is in the
public domain, is authorized for unlimited distribution, and is not copyrighted.
An Introduction To Membrane Techniques For Water Desalination
This course is adapted from the Unified Facilities Criteria of the United States government, which is in the
public domain, is authorized for unlimited distribution, and is not copyrighted.
Desalination At A Glance
Introduction:
By desalination, we will be referring to the production of a useful product water from a feed
water that is too high in inorganic materials (salts) to be useful. The feed water may be
seawater, brackish water, or other “impaired” water that cannot be used directly for potable
or general industrial purposes. Notice that this definition includes the treatment of certain
wastewaters for subsequent reuse.
The principal technologies used in desalination are based on concepts that are fairly easy to
grasp by those with a modest amount of scientific training and/or technical experience. In
practice, however, choices of technology and plant design are usually determined by factors
that might appear minor to the inexperienced. Similarly, new technologies that show great
promise in the laboratory frequently fail for reasons that were earlier overlooked or dismissed
as trivial. Indeed, professional fascination with specific technical elegance has, in some
cases, led researchers to remain oblivious to inherent limitations of a process. Nonetheless,
attention to detail over the past five decades has resulted in dramatic reductions in capital
and operating costs as well as greatly increased plant reliability and performance
Desalination At A Glance
Introduction:
By desalination, we will be referring to the production of a useful product water from a feed
water that is too high in inorganic materials (salts) to be useful. The feed water may be
seawater, brackish water, or other “impaired” water that cannot be used directly for potable
or general industrial purposes. Notice that this definition includes the treatment of certain
wastewaters for subsequent reuse.
The principal technologies used in desalination are based on concepts that are fairly easy to
grasp by those with a modest amount of scientific training and/or technical experience. In
practice, however, choices of technology and plant design are usually determined by factors
that might appear minor to the inexperienced. Similarly, new technologies that show great
promise in the laboratory frequently fail for reasons that were earlier overlooked or dismissed
as trivial. Indeed, professional fascination with specific technical elegance has, in some
cases, led researchers to remain oblivious to inherent limitations of a process. Nonetheless,
attention to detail over the past five decades has resulted in dramatic reductions in capital
and operating costs as well as greatly increased plant reliability and performance
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