Water Desalination & RO
Desalination Course – Lecture 3 Vapor Compression Distillation (VCD)
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Desalination Course – Lecture 3 Vapor Compression Distillation (VCD)
Presented by: Dr. Abeer Moneer
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Water Desalination & RO
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Cleaning Procedures for Composite Polyamide RO Membrane Elements
Note: The Composite Polyamide type of RO membrane elements may not be
exposed to chlorinated water under any circumstances. Any such exposure may
cause irreparable damage to the membrane. Absolute care must be taken
following any disinfection of piping or equipment or the preparation of cleaning or
storage solutions to ensure that no trace of chlorine is present in the feedwater to
the RO membrane elements. If there is any doubt about the presence of chlorine,
perform chemical testing. Neutralize any chlorine residual with a sodium bisulfite
solution, and ensure adequate mixing and contact time to accomplish complete
dechlorination. Dosing rate is 1.8 to 3.0 ppm sodium bisulfite per 1.0 ppm of free
chlorine
Cleaning Procedures for Composite Polyamide RO Membrane Elements
Note: The Composite Polyamide type of RO membrane elements may not be
exposed to chlorinated water under any circumstances. Any such exposure may
cause irreparable damage to the membrane. Absolute care must be taken
following any disinfection of piping or equipment or the preparation of cleaning or
storage solutions to ensure that no trace of chlorine is present in the feedwater to
the RO membrane elements. If there is any doubt about the presence of chlorine,
perform chemical testing. Neutralize any chlorine residual with a sodium bisulfite
solution, and ensure adequate mixing and contact time to accomplish complete
dechlorination. Dosing rate is 1.8 to 3.0 ppm sodium bisulfite per 1.0 ppm of free
chlorine
Desalination and Membrane Technologies: Federal Research and Adoption Issues
In the United States, desalination and membrane technologies are used to augment municipal water supply, produce high-quality industrial water supplies, and reclaim contaminated supplies (including from oil and gas development). Approximately 2,000 desalination facilities larger than
0.3 million gallons per day (MGD) operate in the United States; this represents more than 2% of U.S. municipal and industrial freshwater use. At issue for Congress is what should be the federal role in supporting desalination and membrane technology research and facilities. Desalination issues before the 114th Congress may include how to focus federal research, at what level to support desalination research and projects, and how to provide a regulatory context that protects the environment and public health without disadvantaging desalination’s adoption.
Desalination and Membrane Technologies: Federal Research and Adoption Issues
In the United States, desalination and membrane technologies are used to augment municipal water supply, produce high-quality industrial water supplies, and reclaim contaminated supplies (including from oil and gas development). Approximately 2,000 desalination facilities larger than
0.3 million gallons per day (MGD) operate in the United States; this represents more than 2% of U.S. municipal and industrial freshwater use. At issue for Congress is what should be the federal role in supporting desalination and membrane technology research and facilities. Desalination issues before the 114th Congress may include how to focus federal research, at what level to support desalination research and projects, and how to provide a regulatory context that protects the environment and public health without disadvantaging desalination’s adoption.
Concentrating Solar Power For Seawater Desalination
Introduction:
The general perception of “solar desalination” today comprises only small scale technologies for decentralized water supply in remote places, which may be quite important for the development of rural areas, but do not address the increasing water deficits of the quickly growing urban centers of demand. Conventional large scale desalination is perceived as expensive, energy consuming and limited to rich countries like those of the Arabian Gulf, especially in view of the quickly escalating cost of fossil fuels like oil, natural gas and coal. The environmental impacts of large scale desalination due to airborne emissions of pollutants from energy consumption and to the discharge of brine and chemical additives to the sea are increasingly considered as critical. For those reasons, most contemporary strategies against a “Global Water Crisis” consider seawater desalination only as a marginal element of supply. The focus of most recommendations lies on more efficient use of water, better accountability, re-use of waste water, enhanced distribution and advanced irrigation systems. To this adds the recommendation to reduce agriculture and rather import food from other places. On the other hand, most sources that do recommend seawater desalination as part of a solution to the water crisis usually propose nuclear fission and fusion as indispensable option.
Concentrating Solar Power For Seawater Desalination
Introduction:
The general perception of “solar desalination” today comprises only small scale technologies for decentralized water supply in remote places, which may be quite important for the development of rural areas, but do not address the increasing water deficits of the quickly growing urban centers of demand. Conventional large scale desalination is perceived as expensive, energy consuming and limited to rich countries like those of the Arabian Gulf, especially in view of the quickly escalating cost of fossil fuels like oil, natural gas and coal. The environmental impacts of large scale desalination due to airborne emissions of pollutants from energy consumption and to the discharge of brine and chemical additives to the sea are increasingly considered as critical. For those reasons, most contemporary strategies against a “Global Water Crisis” consider seawater desalination only as a marginal element of supply. The focus of most recommendations lies on more efficient use of water, better accountability, re-use of waste water, enhanced distribution and advanced irrigation systems. To this adds the recommendation to reduce agriculture and rather import food from other places. On the other hand, most sources that do recommend seawater desalination as part of a solution to the water crisis usually propose nuclear fission and fusion as indispensable option.
Basics of Reverse Osmosis
What is Reverse Osmosis?
Reverse Osmosis is a technology that is used to remove a large majority of contaminants from water by
pushing the water under pressure through a semi permeable membrane. This paper is aimed towards an audience that has little of no experience with Reverse Osmosis and will attempt to explain the basics
in simple terms that should leave the reader with a better overall understanding of Reverse Osmosis technology and its applications.
Basics of Reverse Osmosis
What is Reverse Osmosis?
Reverse Osmosis is a technology that is used to remove a large majority of contaminants from water by
pushing the water under pressure through a semi permeable membrane. This paper is aimed towards an audience that has little of no experience with Reverse Osmosis and will attempt to explain the basics
in simple terms that should leave the reader with a better overall understanding of Reverse Osmosis technology and its applications.
Tailoring Advanced Desalination Technologies for 21st Century Agriculture
Abstract: Substantial parts of the U.S., particularly drier landlocked regions, are facing acute water shortages and water quality issues that decrease agricultural productivity. Reduced crop yields cause billions of dollars in losses annually, affecting the livelihoods of thousands. A combination of population growth, inefficient agricultural practices, and resource demanding consumption trends is only expected to increase pressure on our water supplies. This research proposal seeks to address water and food security issues by cost-effectively and energy-efficiently enhancing water quality and water supply in greenhouses; a $22.93 billion dollar industry in 2017 that is rapidly growing at an annual rate of 8.92%. Greenhouses widely practice desalination of salty irrigation water to improve their operations. However, currently used desalination methods do not tailor greenhouse waters based on crop requirements. This work investigates a fully integrated desalination solution that treats and tailors brackish source waters ingreenhouses to save fertilizer and water. Specifically, this project experimentally studies multi-ion transport in and assesses the economic viable of monovalent selective electrodialysis (MSED). MSED allows for the selective removal of monovalent ions damaging to crops and the retention of divalent ions beneficial for crops, unlike the widely used reverse osmosis (RO), which removes all ions from greenhouse source water. First, we evaluate the techno-economic feasibility of MSED compared to other brackish desalination technologies for agricultural applications, based on primary market research we conduct with over 70 greenhouses.
These include conventional technologies, such as reverse osmosis (RO) and electrodialysis (ED), and advanced technologies, such as closed circuit reverse osmosis (CCRO). The analysis determines the levelized costs of water, the capital costs and energy requirements of these technologies, and how these vary with feed salinity, system capacity and recovery ratio. Then, we build a bench-scale setup to experientially characterize MSED membrane properties, including monovalent selectivity, ion transport, limiting current and resistance, for multiple brackish feedwaters and for two sets of MSED membranes: the widely used Neosepta ACS/CMS membranes and the new Fujifilm Type 16 membranes. Both MSED membranes show notable monovalent selectivity for all tested compositions, reflecting the potential of the technology for selective desalination in greenhouses. The measurements are compared to a model for MSED in multi-ion solutions. The model predicts multi-ion transport for the Neosepta and Fujifilm MSED systems within 6% and 8%, respectively.
Tailoring Advanced Desalination Technologies for 21st Century Agriculture
Abstract: Substantial parts of the U.S., particularly drier landlocked regions, are facing acute water shortages and water quality issues that decrease agricultural productivity. Reduced crop yields cause billions of dollars in losses annually, affecting the livelihoods of thousands. A combination of population growth, inefficient agricultural practices, and resource demanding consumption trends is only expected to increase pressure on our water supplies. This research proposal seeks to address water and food security issues by cost-effectively and energy-efficiently enhancing water quality and water supply in greenhouses; a $22.93 billion dollar industry in 2017 that is rapidly growing at an annual rate of 8.92%. Greenhouses widely practice desalination of salty irrigation water to improve their operations. However, currently used desalination methods do not tailor greenhouse waters based on crop requirements. This work investigates a fully integrated desalination solution that treats and tailors brackish source waters ingreenhouses to save fertilizer and water. Specifically, this project experimentally studies multi-ion transport in and assesses the economic viable of monovalent selective electrodialysis (MSED). MSED allows for the selective removal of monovalent ions damaging to crops and the retention of divalent ions beneficial for crops, unlike the widely used reverse osmosis (RO), which removes all ions from greenhouse source water. First, we evaluate the techno-economic feasibility of MSED compared to other brackish desalination technologies for agricultural applications, based on primary market research we conduct with over 70 greenhouses.
These include conventional technologies, such as reverse osmosis (RO) and electrodialysis (ED), and advanced technologies, such as closed circuit reverse osmosis (CCRO). The analysis determines the levelized costs of water, the capital costs and energy requirements of these technologies, and how these vary with feed salinity, system capacity and recovery ratio. Then, we build a bench-scale setup to experientially characterize MSED membrane properties, including monovalent selectivity, ion transport, limiting current and resistance, for multiple brackish feedwaters and for two sets of MSED membranes: the widely used Neosepta ACS/CMS membranes and the new Fujifilm Type 16 membranes. Both MSED membranes show notable monovalent selectivity for all tested compositions, reflecting the potential of the technology for selective desalination in greenhouses. The measurements are compared to a model for MSED in multi-ion solutions. The model predicts multi-ion transport for the Neosepta and Fujifilm MSED systems within 6% and 8%, respectively.
A Primer On Brackish And Seawater Desalination
Abstract: This publication was produced as an activity of the Texas Living Waters Project. This project
is a collaborative effort of the National Wildlife Federation, Environmental Defense, and the Lone
Star Chapter of the Sierra Club. The goals of the project are to 1) ensure adequate water for people
and environmental needs, 2) reduce future demand for water and foster efficient and sustainable use
of current water supplies, 3) educate the public and decision makers about the impact of wasteful
water use and the opportunities for water conservation, and 4) involve citizens in the decision
making process for water management.
A Primer On Brackish And Seawater Desalination
Abstract: This publication was produced as an activity of the Texas Living Waters Project. This project
is a collaborative effort of the National Wildlife Federation, Environmental Defense, and the Lone
Star Chapter of the Sierra Club. The goals of the project are to 1) ensure adequate water for people
and environmental needs, 2) reduce future demand for water and foster efficient and sustainable use
of current water supplies, 3) educate the public and decision makers about the impact of wasteful
water use and the opportunities for water conservation, and 4) involve citizens in the decision
making process for water management.
Desalination and Water Treatment
Abstract:
This study proposes a simple design method of the Reverse osmosis (RO) system in RO brackish water desalination plants. This method is based on the application of maximum available recovery without scaling of any of the compounds present in the water as silica, calcium carbonate, calcium sulfate, barium sulfate, strontium sulfate, and calcium fluoride, and membrane manufacturer design guidelines, and the plant production. Although the method was originally
conceived for application to subterranean brackish waters in the Canary Islands, Spain (principally Gran Canaria, Fuerteventura and Tenerife), it can be extrapolated to other types of region and water treatable with RO systems. The required input data are the chemical composition of the feed water, pH, temperature, silt density index membrane manufacturer design guidelines, and the plant production. The programmed method then determines the design of the RO system. The method whose procedure is described graphically and analytically can be used as an aid in design optimization of RO brackish water desalination plants with acid-free pretreatment processes and only the use of scale inhibitor using spiral wound membranes. Practical applications are presented. The final results for different types of feed water and capacities are showed.
Desalination and Water Treatment
Abstract:
This study proposes a simple design method of the Reverse osmosis (RO) system in RO brackish water desalination plants. This method is based on the application of maximum available recovery without scaling of any of the compounds present in the water as silica, calcium carbonate, calcium sulfate, barium sulfate, strontium sulfate, and calcium fluoride, and membrane manufacturer design guidelines, and the plant production. Although the method was originally
conceived for application to subterranean brackish waters in the Canary Islands, Spain (principally Gran Canaria, Fuerteventura and Tenerife), it can be extrapolated to other types of region and water treatable with RO systems. The required input data are the chemical composition of the feed water, pH, temperature, silt density index membrane manufacturer design guidelines, and the plant production. The programmed method then determines the design of the RO system. The method whose procedure is described graphically and analytically can be used as an aid in design optimization of RO brackish water desalination plants with acid-free pretreatment processes and only the use of scale inhibitor using spiral wound membranes. Practical applications are presented. The final results for different types of feed water and capacities are showed.
Desalination Plant Basis Of Design
Overview:
The project potable water requirements will be provided using single desalination plant with the Grand Bahama Port Authority water supply serving as the backup source. The overall desalination treatment process will consist of feedwater pumping, bag filtration, optional media filtration, the addition of a scale
inhibitor, cartridge filtration, membrane separation, forced air degasification, re-pumping, and post treatment. Provisions have been included to bypass the post treatment systems for the production of irrigation water. The post aeration re-pump station will be designed to transfer either type of water to the
appropriate storage tanks located within the project. Membrane concentrate will be disposed via an injection well to be constructed as part of this project.
The desalination process will consist of a dual treatment units or “trains” each equipped with a positive displacement axial piston first pass membrane feed pump, first pass membrane array, energy recovery system, second pass membrane feed pump, second pass membrane array, high- and low-pressure
piping and instrumentation. The second pass system is designed to treat up to 60 percent of the first pass permeate. A membrane cleaning/flush system will be provided. The membrane post treatment will be designed to receive the flow from both units and consists of a forced air degasified, repumping, recarbonation, calcium carbonate up flow contactors to boost finished water hardness and alkalinity concentrations; and three chemical feed systems for the metering of a corrosion inhibitor, dilute hydrochloric acid for pH adjustment and sodium hypochlorite for residual disinfection. The final pH and chlorine residual will be controlled and recorded by a separate system. The following sections describe the various aspects of the facility in greater detail. Process flow
schematics are presented in Appendix A.
Desalination Plant Basis Of Design
Overview:
The project potable water requirements will be provided using single desalination plant with the Grand Bahama Port Authority water supply serving as the backup source. The overall desalination treatment process will consist of feedwater pumping, bag filtration, optional media filtration, the addition of a scale
inhibitor, cartridge filtration, membrane separation, forced air degasification, re-pumping, and post treatment. Provisions have been included to bypass the post treatment systems for the production of irrigation water. The post aeration re-pump station will be designed to transfer either type of water to the
appropriate storage tanks located within the project. Membrane concentrate will be disposed via an injection well to be constructed as part of this project.
The desalination process will consist of a dual treatment units or “trains” each equipped with a positive displacement axial piston first pass membrane feed pump, first pass membrane array, energy recovery system, second pass membrane feed pump, second pass membrane array, high- and low-pressure
piping and instrumentation. The second pass system is designed to treat up to 60 percent of the first pass permeate. A membrane cleaning/flush system will be provided. The membrane post treatment will be designed to receive the flow from both units and consists of a forced air degasified, repumping, recarbonation, calcium carbonate up flow contactors to boost finished water hardness and alkalinity concentrations; and three chemical feed systems for the metering of a corrosion inhibitor, dilute hydrochloric acid for pH adjustment and sodium hypochlorite for residual disinfection. The final pH and chlorine residual will be controlled and recorded by a separate system. The following sections describe the various aspects of the facility in greater detail. Process flow
schematics are presented in Appendix A.
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